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On the complex influence of the experimental parameters and the properties of the substances on the representation of solid-liquid transitions studied with a differential scanning calorimeter

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Abstract

Due to the increasing importance of quantified results of dynamic calorimetric measurements, the influence of single experimental parameters has been studied by some authors. We found that these results can be represented correctly only in a complex form. According to this experience, the experimental parameters were changed on the basis of statistically planned experiments. The numerous measurements were carried out with samples of indium, 1,3-dinitrobenze and polyethylene prepared in different ways. The results were evaluated in a complex form. The evaluation of the experimental data revealed a significant influence of the substance properties and the experimental parameters.

Zusammenfassung

Die zunehmende Bedeutung quantifizierbarer Ergebnisse von dynamischen kalorimetrischen Messungen veranlasste die Autoren [1–9] zur Untersuchung des Einflusses einzelner experimenteller Parameter. Nach unseren Erfahrungen können diese Ergebnisse nur in komplexer Form dargestellt werden. Entsprechend wurden die Versuchsbedingungen nach einem statistischen Plan variiert. Zahlreiche Messungen wurden mit unterschiedlich präparierten Indium-, 1,3-Dinitrobenzen- und Polyethylen-Proben durchgeführt und die Ergebnisse in komplexer Form ausgewertet. Dabei zeigte sich ein signifikanter Einfluss der Probeneigenschaften und der Versuchsbedingungen.

Резуме

Исходя из значимости количественных результатов динамич еских калориметриче ских измерений, рядом авто ров было изучено влия ние параметров одного эк сперимента. В настоящ ем сообщении показано, ч то эти результаты мог ут быть представлены коррек тно только в комплексной форме. В связи с этим, эксперим ентальные параметры были измен ены на основании статических диаграм м экспериментов. Пров едены многочисленные эксп ерименты с образцами индия, 1,3-динитробензол а и полиэтилена, получ енных различными способам и. Оценка результатов, проведе нная в комплексной фо рме, показала значительн ое влияние свойств ве щества и экспериментальных параметров.

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References

  1. E. Pella and M. Nebuloni, J. Thermal Anal., 3 (1971) 229.

    Google Scholar 

  2. A. A. van Dooren and B. W. Müller, Thermochim. Acta, 49 (1981) 151.

    Article  Google Scholar 

  3. A. A. van Dooren and B. W. Müller, Thermochim. Acta, 49 (1981) 163.

    Article  Google Scholar 

  4. A. A. van Dooren and B. W. Müller, Thermochim. Acta 49 (1981) 175.

    Article  Google Scholar 

  5. A. A. van Dooren and B. W. Müller, Thermochim. Acta 49 (1981) 185.

    Article  Google Scholar 

  6. A. A. van Dooren and B. W. Müller, Thermochim. Acta 49 (1982) 115.

    Article  Google Scholar 

  7. A. A. van Dooren, Anal. Proc., 19 (1982) 554.

    Google Scholar 

  8. K. Krishnan, K. N. Ninan and P. M. Madhusudanan, Thermochim. Acta 71 (1983) 305.

    Article  Google Scholar 

  9. P. Navard and J. M. Handin, J. Thermal Anal., 29 (1984) 405.

    Google Scholar 

  10. ASMW, Fachgebiet Stoffeigenschaften, Prüfbericht, 1/87, Berlin.

  11. G. Lombardi, For Better Thermal Analysis, 2nd Ed., Rome 1980.

  12. H. Utschick, B. Gobrecht, C. Fleischhauer, A. Treffurth and H. Müller, Wiss. Z. Univ. Halle/Wittenberg, 3 (1988) in preparation.

  13. G. Willmann, Freseniuz Z. Anal. Chem., 269 (1974) 257.

    Article  Google Scholar 

  14. R. Altmann, G. Brandes, O. Regen and J. Schneider, Chem.-techn. Stoffwerte-eine Datensammlung, VEB Deutscher Verlag für Grundstoffindustrie, Leipzig 1984.

    Google Scholar 

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Authors and Affiliations

  1. Martin Luther University Halle/Wittenberg, 4020, Halle, Germany

    H. Utschick, B. Gobrecht, C. Fleischhauer, A. Treffurth & H. Müller

  2. Kombinat VEB Chemische Werke Buna, 4212, Schkopau, Germany

    B. Gobrecht, C. Fleischhauer & H. Müller

  3. VEB Chemiekombinat Bitterfeld, 4400, Bitterfeld, Germany

    A. Treffurth

Authors
  1. H. Utschick
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  2. B. Gobrecht
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  3. C. Fleischhauer
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  4. A. Treffurth
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  5. H. Müller
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Utschick, H., Gobrecht, B., Fleischhauer, C. et al. On the complex influence of the experimental parameters and the properties of the substances on the representation of solid-liquid transitions studied with a differential scanning calorimeter. Journal of Thermal Analysis 33, 297–304 (1988). https://doi.org/10.1007/BF01914615

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