Skip to main content
SpringerLink
Log in

A thermal analysis study of lanthanide adipate hydrates

  • Published:
Journal of thermal analysis Aims and scope Submit manuscript

Abstract

The multi-step dehydration and decomposition of trivalent lanthanide adipate hydrates has been investigated by TG, DTG and DTA, together with infrared study of these compounds and the corresponding intermediate decomposition products. X-ray diffraction data for adipate complexes of general stoichiometry Ln2(C6H8O4)3· 10H2O, where Ln=La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu are also reported.

Zusammenfassung

Die in mehreren Schritten verlaufende Dehydratisierung und Zersetzung von Adipat-Hydraten der dreiwertigen Lanthanide wurden mittels TG, DTG und DTA untersucht. Diese Verbindungen und bei deren Zersetzung auftretende Zwischenprodukte wurden auch infrarotspektroskopisch charakterisiert. Röntgendiffraktometrische Daten sind für Adipatkomplexe der allgemeinen StöchiometrieLn2(C6H8O4)3·10H2O (Ln=La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb und Lu) angegeben.

РЕжУМЕ

МЕтОДОМ тг, Дтг, ДтА И Ик спЕктРОскОпИИ ИжУЧЕ НА МпОгОстУпЕНЧАтАь ДЕ гИДРАтАцИь И РАжлОжЕНИЕ ДЕкАгИД РАтОВ лАНтАНОИДОВ АД ИпИНОВОИ кИслОты с ОБЩЕИ ФОРМУ лОИ Ln2(C6H8O4)3·10Н2О. МЕтОД Ик спЕ ктРОскОпИИ Был ИспОльжОВАН тАкжЕ Дл ь ИДЕНтИФИкАцИИ пРОМЕжУтОЧНых пРОДУ ктОВ РАжлОжЕНИь. Дль В сЕх ИсхОДНых сОлЕИ пРЕДс тАВлЕНы тАкжЕ ДАННыЕ РЕНтгЕНОстРУктУРНО гО АНАлИжА.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. B. Wunderlich and R. C. Bopp, J. Thermal Anal., 6 (1974) 335.

    Google Scholar 

  2. B. D. Jain, Current Science, India, 32 (1963) 66.

    Google Scholar 

  3. D. J. Riabchikov and E. A. Terentieva, Izv. Acad. Nauk USSR, Otd. Khim. Neorg., 1 (1949) 44.

    Google Scholar 

  4. J. M. Peacook and J. C. James, J. Chem. Soc., (1951) 2233.

  5. J. M. Korenman and D. N. Sokolov, Trudy po Khimii i Khimich. Tekhnol., 2 (1961) 311; Ref. Zh. Khim., (USSR), 1961, 12B 543.

    Google Scholar 

  6. D. N. Shelke and D. W. Jahagirdar, Bull. Chem. Soc. Japan, 49 (1976) 2442.

    Google Scholar 

  7. W. Brzyska and W. Hubicki, Ann. Univ. M. Curie-Skłodowska, Lublin, Sect. AA 23 (1968) 77; Chem. Abstr., 71 (1969) 116998 b.

    Google Scholar 

  8. B. S. Azikov and W. W. Serebrennikov, Trudy Tomsk. Gos. Univ. Ser. Khim., 185 (1965) 111; Chem. Abstr., 66 (1967) 43328 t.

    Google Scholar 

  9. B. S. Azikov and W. W. Serebrennikov, ibid., 185 (1965) 118; Chem. Abstr., 66 (1967) 43327 s.

    Google Scholar 

  10. B. S. Azikov and W. W. Serebrennikov, ibid., 192 (1968) 71; Chem. Abstr., 73 (1970) 72665 a.

    Google Scholar 

  11. A. M. Wynne and J. E. Roberts, Thermochim. Acta, 7 (1973) 159.

    Google Scholar 

  12. A. J. Vogel, J. Chem. Soc., (1929) 722.

  13. K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, J. Wiley, New York-London 1963.

    Google Scholar 

  14. J. Loners and N. Caro, Journ. des Recherches du CNRS, 9 (1957) 107.

    Google Scholar 

  15. W. W. Wendlandt, Analyt. Chem., 30 (1958) 58; 31 (1959) 408.

    Google Scholar 

  16. M. Dąbkowska, J. Polish Chem. (in press).

Download references

Author information

Authors and Affiliations

  1. Institute of Inorganic and General Chemistry, Maria Curie Skłodowska University, 20-031, Lublin, Poland

    M. Dąbkowska

Authors
  1. M. Dąbkowska
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Dąbkowska, M. A thermal analysis study of lanthanide adipate hydrates. Journal of Thermal Analysis 32, 71–77 (1987). https://doi.org/10.1007/BF01914549

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01914549

Keywords

Search

Navigation