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Mass spectral and thermogravimetric studies of some iron(III) binuclear complexes with bridging thiuram disulfide ligands

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Abstract

Mass spectral and thermal studies by TG and DTG of some iron(III) binuclear complexes of the general type Fe2(R2dtc)2(tds∮)X2X/′ have been carried out to determine their modes of decomposition. Fragmentation patterns are given and possible mechanisms are discussed.

Zusammenfassung

Massenspektrometrische und thermische Untersuchungen (TG und DTG) einiger zweikerniger Eisen(III)-Komplexe des allgemeinen Typs (R2dtc)2(tdsℴ)X2X′2 wurden ausgeführt, um deren Zersetzungsmechanismus zu ermitteln. Fragmentspektren werden angegeben und mögliche Mechanismen diskutiert.

Резюме

Проведено масс-спект рометрическое и термическое (ТГ и ДТГ) и сследование некоторых двуядерны х комплексов трехвал ентного желсза общей формулы Fe2(R2dtc)2(tds)X2X′2 с целью устано вления характера их разложения. Приведен а схема их распада и обсужден ме ханизм реакций.

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Authors and Affiliations

  1. Laboratory of Inorganic Chemistry, Aristotelian University, 54006, Thessaloniki, Greece

    G. A. Katsoulos, M. Lalia-Kantouri & F. D. Vakoulis

Authors
  1. G. A. Katsoulos
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  2. M. Lalia-Kantouri
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  3. F. D. Vakoulis
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Katsoulos, G.A., Lalia-Kantouri, M. & Vakoulis, F.D. Mass spectral and thermogravimetric studies of some iron(III) binuclear complexes with bridging thiuram disulfide ligands. Journal of Thermal Analysis 31, 539–546 (1986). https://doi.org/10.1007/BF01914229

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  • DOI: https://doi.org/10.1007/BF01914229

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