Abstract
The thermal decomposition and spectroscopic (reflectance and IR spectra) characterization of the newly synthesized square-pyramidal dioxovanadium(V) complexes of the type NH4[VO2(L)] (L is the dianion of the terdentate ligands salicylaldehyde thiosemicarbazone (ONS), halogen-substituted salicylaldehyde and 2-hydroxy-1-naphthaldehyde S-methylisothiosemicarbazones (ONN)) are described.
Zusammenfassung
Es wird die thermische Zersetzung und spektroskopische Charakterisierung (Reflexionsvermögen und IR-Spektren) neu synthetisierter Dioxovanadium(V)-Komplexe der allgemeinen Formel NH4[VO2(L)] beschrieben, wobei L das Dianion des dreizahnigen Liganden Salicylaldehyd-thiosemicarbazon (ONS), halogensubstituiertes Salicylaldehyd- bzw. 2-Hydroxy-1-naphthaldehyd-S-methyl-isothiosemicarbazon (ONN) ist.
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References
N. V. Gerbeleu, Zhur. Neorg. Khim., 13 (1968) 2467.
V. M. Leovac, N. V. Qerbeleu and V. D. Canich, Zhur. Neorg. Khim., 27 (1982) 918.
A. F. Petrovic, B. Ribár, D. M. Petrovic, V. M. Leovac and N. V. Gerbeleu, J. Coord. Chem., 11 (1982) 239.
Gy. Argay, A. Kálmán, B. Ribár, V. M. Leovac and A. F. Petrovic, Monatsh. Chem., 114 (1983) 1205.
P. Kubelka and F. Munk, Z. Tech. Phys., 12 (1931) 593.
M. J. M. Campbell, Coor. Chem. Rev., 15 (1975) 279.
V. M. Leovac, L. Bjelica and Lj. Jovanovic, Polyhedron, 4 (1985) 233.
A. F. Petrovic, V. M. Leovac, B. Ribár, Gy. Argay and A. Kálmán, Transition Met. Chem., 11 (1986) 207.
W. J. Geary, Coord. Chem. Rev., 7 (1971) 81.
W. P. Griffith and T. D. Wickins, J. Chem. Soc., (A), (1968) 400.
V. M. Leovac and A. F. Petrovic, Transition Met. Chem., 8 (1983) 337.
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Leovac, V.M., Petrovic, A.F., Ivegeš, E.Z. et al. Transition metal complexes with thiosemicarbazide-based ligands. Journal of Thermal Analysis 36, 2427–2439 (1990). https://doi.org/10.1007/BF01913640
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DOI: https://doi.org/10.1007/BF01913640