Skip to main content
SpringerLink
Log in

Thermal behaviour of some nickel(II)-morpholine complexes

  • Published:
Journal of thermal analysis Aims and scope Submit manuscript

Abstract

The preparation of Ni(CN)21.5M (M=morpholine) and the thermal study of this and NiBr23M, Nil24M and Ni(NCS)24M are described. The thermal treatment of these compounds leads to the isolation of Ni(CN)2M, Ni(CN)20.5M, NiBr22M, Nil23M, Nil21.5M, Ni(NCS)22M and Ni(NCS)2M. With the exception of NiBr22M and Ni(NCS)22M, all intermediate species are reported here for the first time. Magnetic and spectral studies have been carried out to determine the mode of coordination and stereochemistry of the complexes. The thermal study includes the determination of stability, apparent activation energy and reaction orders, and reaction enthalpies.

Zusammenfassung

Die Darstellung von Ni(CN)21.5M (M=Morpholin) wird beschrieben. Das thermische Verhalten dieser Verbindung und von NiBr23M, Nil24M und Ni(NCS)24M wird untersucht. Durch thermische Behandlung dieser Verbindungen werden Ni(CN)2M, Ni(CN)20.5M, NiBr22M, Nil23M, Nil21.5M, Ni(NCS)22M und Ni(NCS)2M erhalten. Mit Ausnahme von NiBr22M und Ni(NCS)22M handelt es sich dabei um bisher noch nicht beschriebene Zwischenprodukte. Es wurden magnetische und spektrometrische Untersuchungen ausgeführt, um die Art der Koordinaten und die Stereochemie dieser Komplexe zu ermitteln. Die thermische Untersuchung erstreckt sich auf die Bestimmung der Stabilität, der scheinbaren Aktivierungsenergie und der Reaktionsordnungen sowie der Reaktionsenthalpien.

Резюме

Описано получение ко мплекса Ni(CN)21.5M (M=морфолин), термическое исследо вание которого проведено с овместно с комплекса ми NiBr23M, Nil24M, Ni(NCS)24M. Термическая обработ ка этих комплексов пр иводит к образованию Ni(CN)2M, Ni(CN)20.5M, NiBr22M, Nil23M, Nil21.5M, Ni(NCS)22M, и Ni(NCS)2M. За искл ючением NiBr22M и Ni(NCS)22M, все остальные пр омежуточные соедине ния обнаружены впервые. С целью определения т ипа координации и сте реохимии комплексов, было пров едено исследование их магн итных и спектральных свойств. Термическое исследо вание включало определение их устой чивости, кажущейся эн ергии активации и порядков реакций, а также энтальпий реакций.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. Palazón, J. Gálvez, G. Garcia and G. López, Polyhedron, 2 (1983) 1353.

    Article  Google Scholar 

  2. I. S. Ahuja and I. S. Singh, Transition Metal Chem., 2 (1977) 132.

    Article  Google Scholar 

  3. I. S. Ahuja, Inorg. Chim. Acta, 3 (1969) 110.

    Article  Google Scholar 

  4. G. Marcotrigiano, G. C. Pellacani and C. Petri, Z. anorg. allg. Chem., 408 (1974) 313.

    Article  Google Scholar 

  5. G. Schwarzenbach and H. Flashka, Complexometric Titrations, Methuen, London, 1969, p. 248.

    Google Scholar 

  6. B. N. Figgis and J. Lewis, in Modern Coordination Chemistry, Interscience Publishers Inc., New York, 1960, p. 415.

    Google Scholar 

  7. E. E. Aynsley and W. A. Campbell, J. Chem. Soc., (1958) 1723.

  8. L. Sacconi, I. Bertini and F. Mani, Inorg. Chem., 6 (1967) 262.

    Article  Google Scholar 

  9. F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, Wiley, New York, 1980, p. 790.

    Google Scholar 

  10. A. G. Sharpe, The Chemistry of Cyano Complexes of the Transition Metals, Academic Press, London, 1976, p. 232.

    Google Scholar 

  11. A. Ludi and R. Mugi, Helv. Chim. Acta, 51 (1968) 349.

    Article  Google Scholar 

  12. S. M. Nelson and T. M. Shepherd, J. Inorg. Nucl. Chem., 27 (1965) 2123.

    Article  Google Scholar 

  13. R. J. M. Clark and C. S. Williams, Spectrochim. Acta, 22 (1966) 1081.

    Article  Google Scholar 

  14. D. Vedal, O. H. Ellestad and P. Klaboe, Spectrochim. Acta, 32A (1976) 877.

    Article  Google Scholar 

  15. W. W. Wendlandt, Thermal Methods of Analysis, Wiley, New York, 1974, p. 178.

    Google Scholar 

  16. J. Sestak, Talanta, 13 (1966) 567.

    Article  Google Scholar 

  17. E. S. Freeman and B. Carroll, J. Phys. Chem., 62 (1958) 394.

    Article  Google Scholar 

  18. A. W. Coats and J. P. Redfern, Nature, 201 (1964) 68.

    Google Scholar 

  19. V. Satava, Thermochim. Acta, 2 (1971) 423.

    Article  Google Scholar 

  20. H. E. Kissinger, Anal. Chem., 29 (1957) 1702.

    Article  Google Scholar 

  21. G. O. Piloyan, I. D. Ryabchikov, O. S. Novikova, Nature, 212 (1966) 1229.

    Google Scholar 

  22. J. Zsakó, J. Phys. Chem., 72 (1968) 2406.

    Article  Google Scholar 

  23. V. Satava and F. Skvara, J. Am. Ceram. Soc., 52 (1969) 591.

    Google Scholar 

  24. J. H. Sharp, G. W. Brindley and B. N. Narahari Achar, J. Am. Ceram. Soc., 49 (1966) 379.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Inorganic Chemistry, University of Murcia, Murcia, Spain

    J. Gálvez, J. Palazón, G. López & G. García

Authors
  1. J. Gálvez
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. Palazón
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. López
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. García
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gálvez, J., Palazón, J., López, G. et al. Thermal behaviour of some nickel(II)-morpholine complexes. Journal of Thermal Analysis 29, 465–478 (1984). https://doi.org/10.1007/BF01913456

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01913456

Keywords

Search

Navigation