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Study of the thermal dissociation of processes of nickel(II) and cobalt(II) β-diketonate adducts

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Abstract

Thermal dissociation processes ofβ-diketonate adducts with the composition ML2 · 2B (L = acetylacetone and its substituted derivatives;M = Ni, Co;B = H2O, BuNH2CH3OH, Py, NH3) were investigated. Kinetics of dissociation were studied in a flow reactor. For dehydration processes a compensation relationship is observed (lgA=E+b), demonstrating analogous mechanisms.

A semi-quantitative series of the thermodynamic stabilities of the dihydrates is obtained from experimental data at quasi-equilibrium conditions (Q-derivatograph).

Zusammenfassung

Es wurden die thermischen Dissoziationsprozesse vonβ-Diketonataddukten der Zusammensetzung ML2 · 2B (L=Azetylazeton und dessen substituierte Abkömmlinge;M=Ni, Co;B=H2O, BuNH2, CH3OH, Py, NH3) untersucht. Die Kinetik der Dissoziation wurde in einem Flowreaktor untersucht. Als Beweis für die Ähnlichkeit der Mechanismen der Dehydrierungsprozesse konnte eine lgA=aE+b Beziehung festgestellt werden. Von unter Quasi-Gleichgewichtsbedingungen gewonnenen Daten konnte eine semiquantitative Serie der thermodynamischen Stabilitäten der Dihydrate abgeleitet werden (Q-Derivatograph).

Резюме

Изучены процессы тер мической диссоциаци и аддуктовβ-дикетонат ов состава ML2·2B (L = ацетилацетон и ег о замещенные произво дные;M= Ni, Co;B=H2O, BuNH2, CH3OH, Py, NH3). Кинетика диссоци ации исследована в проточном реакторе; д ля процессов дегидратации наблюд ается компенсационн ая зависимость (lgA=aEs+b) свиде тельствующая об аналогии в механиз ме. Полуколичественн ый ряд термодинамической у стойчивости дигидра тов получен по данным экс перимента в квазирав новесных условиях (Q-дериватогр аф).

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References

  1. M. Z. Gurevich, T. M. Sas, N. E. Lebedeva, V. V. Zelentsov and B. D. Stepin, Zh. neorg. khim., 14 (1972) 1073.

    Google Scholar 

  2. M. Z. Turevich, T. M. Sas, V. B. Zelentsov, B. D. Stepin and N. E. Mazepova, Zh. neorg. khim., 20 (1975) 452.

    Google Scholar 

  3. E. A. Mazurenko, Zh. N. Bublik and S. V. Volkov, Ukr. khim. zs., 45 (1979) 591.

    Google Scholar 

  4. A. Aikawa, H. Kawamoto and M. Abe, J. Inorg. Nucl. Chem., 34 (1972) 1763.

    Article  Google Scholar 

  5. J. Yoshida, H. Kobayashi and K. Ueno, J. Inorg. Nucl. Chem., 35 (1973) 4061.

    Article  Google Scholar 

  6. J. Yoshida, H. Kobayashi and K. Ueno, Bull. Chem. soc. Japan, 45 (1972) 1411.

    Google Scholar 

  7. J. H. van Fassel and W. W. Wendlandt, J. Amer. Chem. Soc., 82 (1960) 4821.

    Article  Google Scholar 

  8. W. W. Wendlandt, J. L. Berg and G. R. Norton, J. Phys. Chem., 64 (1960) 1289.

    Google Scholar 

  9. A. G. Jess, A. Baks, D. L. Stufkens and K. Vriese, Inorg. Chim. Acta, 29 (1978) 177.

    Article  Google Scholar 

  10. M. A. Bernard, A. Busnot and N. Decker, Bull. Soc. Chim. France, 6 (1971) 1995.

    Google Scholar 

  11. M. A. Bernard, M. Borel and N. Decker, Bull. Soc. Chim. France, 9 (1971) 3144.

    Google Scholar 

  12. M. A. Bernard and N. Decker, Bull. Soc. Chim. France, 4 (1972) 1288.

    Google Scholar 

  13. M. A. Bernard and F. Busnot, Bull. Soc. Chim. France, 9 (1969) 3061.

    Google Scholar 

  14. M. A. Bernard, A. Busnot and F. Busnot, Bull. Soc. Chim. France, 8 (1970) 2867.

    Google Scholar 

  15. I. K. Igumenov, V. M. Gorbachev and A. N. Popov, Izv. Sibirsk. otd. AN SSSR, ser. khim. nauk, (1973) ser. 2. No. 4, 33.

  16. J. Paulik and F. Paulik, Anal. Chim. Acta 60 (1972) 127.

    Article  Google Scholar 

  17. F. Paulik and J. Paulik, J. Thermal Anal., 5 (1973) 253.

    Google Scholar 

  18. V. A. Logvinenko, Thermal analysis of co-ordination compounds and clathrates (in Russian). Nauk, Novosibirsk, 1982.

    Google Scholar 

  19. A. V. Nikolaev, V. A. Logvinenko, Ya. Šesták and V. Škvara, Dokl. AN SSSR, 231 (1976) 146.

    Google Scholar 

  20. H.H. Horowitz and G. Metzger, Anal. Chem., 35 (1963) 1464.

    Article  Google Scholar 

  21. N. E. Fedotova and I. K. Igumenov, Izv. Sibirsk. Otdel. AN SSSR, ser. khim. nauk. (1984) ser. 3. No. 8, 20.

  22. I. K. Igumenov, N. E. Fedotova and S. V. Zemskov, Koord. khimiya, 6 (1980) 1903.

    Google Scholar 

  23. I. K. Igumenov and A. N. Popov, Izv. Sibirsk. Otdel. AN SSSR, ser. khim. nauk, (1972) No. 5, 15.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Department of the Academy of Sciences of the U.S.S.R., Novosibirsk, USSR

    V. A. Logvinenko, N. E. Fedotova, I. K. Igumenov & G. V. Gavrilova

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  1. V. A. Logvinenko
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  2. N. E. Fedotova
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  3. I. K. Igumenov
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  4. G. V. Gavrilova
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Logvinenko, V.A., Fedotova, N.E., Igumenov, I.K. et al. Study of the thermal dissociation of processes of nickel(II) and cobalt(II) β-diketonate adducts. Journal of Thermal Analysis 34, 259–268 (1988). https://doi.org/10.1007/BF01913392

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  • DOI: https://doi.org/10.1007/BF01913392

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