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Kinetics and Mechanism of Thermal Decomposition of Bis(η3-Allyl)Nickel Complexes

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Abstract

The kinetics of thermal decomposition of bis(η3-allyl) nickel complexes in various media is studied. The specific features of the mechanism are determined, including the combination of the stages of trans-cis isomerization of Niall2 and the bimolecular decomposition of the cis-isomer with diallyl formation. The effect of autocatalytic decomposition of complexes with metallic nickel is been detected. The qualitative dependences of the process rate on the nature of the solvent and the structure of the allyl ligand are determined. The activation parameters of individual steps, consistent with quantum chemical calculations, are found.

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ACKNOWLEDGMENTS

This work was supported by the Russian Foundation for Basic Research (project 17-03-00463).

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Authors and Affiliations

  1. MIREA–Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies), 119571, Moscow, Russia

    V. R. Flid, V. V. Zamalyutin, R. S. Shamsiev & E. A. Katsman

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  1. V. R. Flid
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  2. V. V. Zamalyutin
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  3. R. S. Shamsiev
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  4. E. A. Katsman
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Correspondence to V. R. Flid.

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Dedicated to Academician of the Russian Academy of Sciences Ilya Iosifovich Moiseev in connection with his jubilee

Translated by Andrey Zeigarnik

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Flid, V.R., Zamalyutin, V.V., Shamsiev, R.S. et al. Kinetics and Mechanism of Thermal Decomposition of Bis(η3-Allyl)Nickel Complexes. Kinet Catal 60, 113–117 (2019). https://doi.org/10.1134/S0023158419020150

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  • DOI: https://doi.org/10.1134/S0023158419020150

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