Abstract
The title compound was obtained from a CS2 solution of bis(2,2′-dipyridylamido)copper(II), by insertion of solvent into this complex. In the structure of the dithiocarbamate the metal atom is approximately square-planar coordinated by four S atoms from two chelating ligands. Considering the long interactions between the metal center and the S(2) atom from a centrosymmetrically related complex [Cu(1)...S(2)=3.230 Å], double bridged dimers are formed with the copper atoms in an elongated square-pyramidal coordination. The crystals are monoclinic, space groupP2 1/n witha=14.549(3),b=11.662(3)c=15.329(4) Å and β=114.79(2)°.
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Manotti Lanfredi, A.M., Ugozzoli, F. & Camus, A. X-ray crystal structure of the copper(II)bis(2,2′-dipyridyl)dithiocarbamate, produced by an unusual reaction of CS2 with Cu−N bonds. J Chem Crystallogr 26, 141–145 (1996). https://doi.org/10.1007/BF01669731
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DOI: https://doi.org/10.1007/BF01669731