Skip to main content
SpringerLink
Log in

The crystal and molecular structure of an epoxide, C30H50O

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The compound C30H50O (7β,8β-epoxy-9(87)-abeofriedelane),M r=376.33, orthorhombic, P212121,a=11.819(1) Å,b=14.381(2)Å,c=15.402(2)Å,Z=4,D c=1.083 gm cm−3,R=0.055, for 1643 reflections (withI>2σ) out of 1743 unique reflections. The three dimensional structure determination is done to characterize the conformation of this series of compounds which has good promise for drug and for rational understanding of the reaction mechanism in the olefin stereochemistry and the structural basis of synthesis of these natural products.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • Brodasky, T. F., Stroman, D. W., Dietz, A., and Mizsak, S. (1983)J. Antibiot. 36, 950.

    Google Scholar 

  • Box, S. J., Gilpin, M. L., M. Gwynn, Hanscomb, G., Spear, S. R., and Brown, A. G. (1983)J. Antibiot. 36, 1631.

    Google Scholar 

  • Closse, A., Mauli, R., and Sigg, H. P. (1966)Helv. Chim. Acta 49, 204.

    Google Scholar 

  • Jefford, Charles W., and Bernardinelli, G. (1985)Tetrahedron Lett.26, 615–618.

    Google Scholar 

  • Kamano, Y., Pettit, G. R., Inoue, M., Tozawa, M., and Komeichi, J. (1977)J. Chem. Res. (M) 840.

  • Marumo, S., Saski, K., and Suzuki, S. (1964)J. Am. Chem. Soc. 86, 4507.

    Google Scholar 

  • Merrien, A., Meunier, B., Pascard, C., and Polonsky, J. (1981)Tetrahedron 37, 2303–2306.

    Google Scholar 

  • Motherwell, W. D. S., and Clegg, W. (1978)PLUTO, Program for plotting molecular and crystal structures. (Univ. of Cambridge, England).

    Google Scholar 

  • Polonsky, J., Varon, Z., Marazano, Cn., Arnoux, B., Pettit, G. R., Schmidt, J. M., Ochi, M., and Kotsuki, H. (1979),Experienta 35, 387.

    Google Scholar 

  • Read, G., and Vining, L. C. (1963)Chem. Ind. (London) 1239.

  • Sharpless, K. B., Umbreit, M. A., Nich, M. T., and Flood, T. C. (1972)J. Am. Chem. Soc. 94, 6538.

    Google Scholar 

  • Sengupta, P., Chakraborty, A. K., Duffield, A. M., Durham, L. J., and Djerass, C. (1968)Tetrahedron 24, 1205–1213.

    Google Scholar 

  • Sheldrick, G. M. (1976)SHELX76, Program for crystal structure determination. (Univ. of Cambridge, England).

    Google Scholar 

  • Sheldrick, G. M. (1986)SHELXS86, Program for the solution of crystal structures. (Univ. of Gottingen, Germany).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Biophysics, Bose Institute, 700054, Calcutta, India

    Indrani Dey, B. P. Mukhopadhyay & Asok Banerjee

Authors
  1. Indrani Dey
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. P. Mukhopadhyay
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Asok Banerjee
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Dey, I., Mukhopadhyay, B.P. & Banerjee, A. The crystal and molecular structure of an epoxide, C30H50O. J Chem Crystallogr 24, 387–390 (1994). https://doi.org/10.1007/BF01665891

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01665891

Keywords

Search

Navigation