Skip to main content
Log in

Analytic solution of Percus-Yevick equation for fluid of hard spheres

  • Published:
Czechoslovak Journal of Physics B Aims and scope

Abstract

A new method of analytic solution of the Percus-Yevick equation for the radial distribution functiong(r) of hard-sphere fluid is proposed. The original non-linear integral equation is reduced to non-homogeneous linear integral equation of Volterra's type of the second order. The kernel of this new equation has a polynomial form which allows to find analytic expression forg(r) itself without using the Laplace transformation. In addition, the first three moments of the total correlation function can be found.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Boublík T., et al., Statistická termodynamika kapalin a kapalných směsí. Academia, Praha (in press).

  2. Percus K., Yevick G. J., Phys. Rev.110 (1957), 1.

    Google Scholar 

  3. Alder B. J., Hecht C. E., J. Chem. Phys.50 (1969), 2032.

    Google Scholar 

  4. Wertheim M. S., Phys. Rev. Letters10 (1963), 321.

    Google Scholar 

  5. Wertheim M. S., J. Math. Phys.5 (1964), 643.

    Google Scholar 

  6. Throop G. J., Bearman R. J., J. Chem. Phys.42 (1965), 2408.

    Google Scholar 

  7. Mandel F., et al., J. Chem. Phys.52 (1970), 3315.

    Google Scholar 

  8. Smith W. R., Henderson D., Mol. Phys.19 (1970), 411.

    Google Scholar 

  9. Michlin S. G., Integrální rovnice. Prírodovědecké nakl., Praha 1952.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nezbeda, I. Analytic solution of Percus-Yevick equation for fluid of hard spheres. Czech J Phys 24, 55–62 (1974). https://doi.org/10.1007/BF01596443

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01596443

Keywords

Navigation