Abstract
Binding energy of the electronic polaron in molecular condensates is examined in a simple model permitting quantum dynamical as well as classical microelectrostatic energy calculations. Quantum effects in the electron (hole) polarization energy due to dipole-dipole correlations (and their distortion by an excess charge) among neutral molecules and molecular ion are studied. It is found that these quantum effects lead to a decrease of the magnitude of the electron (hole) polarization energy in realistic situations.
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Čápek, V. Quantum effects in the electronic polarization energy in molecular systems. Czech J Phys 28, 773–780 (1978). https://doi.org/10.1007/BF01595999
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DOI: https://doi.org/10.1007/BF01595999