Abstract
The current flowing through the Pt/NaCl interface was interpreted as a superposition of charge transfer current and displacement current charging the nonlinear capacity of the interface. Experimentally found values of the capacity and conductivity were employed for constructing a simplified equivalent circuit of the NaCl crystal in contact with Pt electrodes. Experimentally observed charging and discharging currents are presented and compared with numerically calculated ones for the considered nonlinear circuits.
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References
Friauf R. J., J. Chem. Phys.22 (1954), 1329.
Allnatt A. R., Jacobs P. W. M., J. Phys. Chem. Solids19 (1961), 281.
Jacobs P. W. M., Maycock J. N., J. Chem. Phys.39 (1963), 757.
Kessler A., Mariani E., Czech. J. Phys.B 14 (1964), 757.
Kessler A., Mariani E., Czech. J. Phys.B 15 (1965), 407.
Wintle H. J., Rolfe J., Can. J. Phys.44 (1966), 965.
Wimmer J. M., Tallan N. M., J. Appl. Phys.37 (1966), 3728.
Allnatt A. R., Jacobs P. W. M., Maycock J. N., J. Chem. Phys.43 (1965), 2526.
Riveros H. G., Rosas L., Rev. Mexic. de Fis.17 (1968), 33.
Beaumont J. H., Jacobs P. W. M., J. Phys. Chem. Sol.28 (1967), 657.
Jaffe G., Ann. d. Phys.16 (1933), 217, 249.
Macdonald J. R., Phys. Rev.92 (1953), 4.
Macdonald J. R., Brachman M. K., Proc. IRE43 (1955), 71.
Macdonald J. R., J. Chem. Phys.54 (1970), 2026.
Miliotis D., Yoon D. N., J. Phys. Chem. Solids30 (1969), 1241.
Kessler A., Mariani E., J. Phys. Chem. Solids29 (1968), 1079.
Gibbs D. F., Jones D. W., J. Phys.C 2 (1969), 1392.
Raleigh D. O., J. Phys. Chem. Solids29 (1968), 261.
Mitoff S. P., Charles R. J., J. Appl. Phys.43 (1972), 927.
Lányi Š., Mariani E., J. Phys. E: Sci. Inst.4 (1971), 317.
Lányi Š., (prepared for publication).
Vetter K. J., Elektrochem. Kinetik, Springer, Berlin 1961.
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Lányi, Š., Harašta, V. Interpretation of charging and discharging currents in NaCl by electrode polarization. Czech J Phys 23, 1084–1092 (1973). https://doi.org/10.1007/BF01586847
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DOI: https://doi.org/10.1007/BF01586847