Abstract
The structure of 6-t-butyl-1,2-naphthoquinone-1-oxime was determined by direct methods by the use of MoKα diffractometer data and was refined toR = 0.12. The crystals are monoclinic:a = 8.32(1),b = 6.70(1),c = 11.14(1) Å, β = 101(1) °,Z = 2,P21/m. The molecule is crystallographically flat and lies in a mirror plane. Pronounced diffuse scattering on [010] oscillation photographs is caused by disorder in the orientation of thet-butyl group. The compound occurs in the oxime form, and not as a 1,2-nitroso naphthol.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Feigl, F. (1949).Chemistry of Specific, Selective and Sensitive Reactions (Academic Press, New York), P. 251.
Hegetschweiler, H., Hancock, R., and Green, B. (1975). Private communication of unpublished results.
Saarinen, H., and Korvenranta, J. (1975).Acta Chem. Scand. A29, 409.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Boeyens, J.C.A. Crystal and molecular structure of 6-t-butyl-1,2-naphthoquinone-1-oxime. Journal of Crystal and Molecular Structure 6, 217–222 (1976). https://doi.org/10.1007/BF01570983
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01570983