Skip to main content
SpringerLink
Log in

Structure and absolute configuration of 10-chloro-10-sulfinylcamphor, C10H13ClO2S

  • Published:
Journal of Crystallographic and Spectroscopic Research Aims and scope Submit manuscript

Abstract

The structure of the title compound, C10H13ClO2S, was determined by X-rays:M r =232.72, monoclinic, space groupP21,a=6.4902(6),b=12.022(1),c=14.130(3) Å,β=103.11(1)°,V c =1073.7 Å3,Z=4,D x =1.44 Mg m−3. MoKα radiation (graphite crystal monochromator, λ=0.71069 Å),μ(MoKα)=4.9 cm−1,F(000)=342,T=293 K. Final conventionalR-factor=0.035 for 2221 observed reflections and 252 variables. The structure was solved usingDirdif. The absolute configuration of the structure is reported. The two independent molecules differ primarily in the orientation of the sulfine group with respect to the camphor moiety.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • Beurskens, G., Noordik, J. H., and Beurskens, P. T. (1980)Cryst. Struct. Commun. 9, 23–28.

    Google Scholar 

  • Beurskens, P. T., Bosman, W. P., Doesburg, H. M., Van den Hark, Th. E. M., Prick, P. A. J., Noordik, J. H., Beurskens, G., Gould, R. O., and Parthasarathi, V. (1982)Conformation in Biology, R. Srinivasan and R. H. Sarma, eds. (Adenine Press, New York), pp. 389–406.

    Google Scholar 

  • Grant, D. F., and Gabe, E. J. (1978)J. Appl. Cryst. 11, 114–120.

    Google Scholar 

  • International Tables for X-ray Crystallography (1974) Vol. IV (Kynoch Press, Birmingham).

  • Lehman, M. S., and Larsen, F. K. (1974)Acta Cryst. A 30, 580–584.

    Google Scholar 

  • Motherwell, W. D. S. (1976) PLUTO, a program for plotting molecular and crystal structures (University Chemical Laboratory, Cambridge, England).

    Google Scholar 

  • North, A. C. T., Philips, D. C., and Mathews, F. S. (1968)Acta Cryst. A 24, 351–359.

    Google Scholar 

  • Porskamp, P. A. T. W., Haltiwanger, R. C., and Zwanenburg, B. (1983)Tetrahedron Lett. 24, 2035–2038.

    Google Scholar 

  • Sheldrick, G. M. (1976)Shelx, a program for crystal structure determination (University Chemical Laboratory, Cambridge, England).

    Google Scholar 

  • Walker, N., and Stuart, D. (1983)Acta Cryst. A 39, 158–166.

    Google Scholar 

  • Wedekind, E., and Schenk, D. (1911)Ber. Dtsch. Chem. Ges. 44, 198.

    Google Scholar 

  • Zwanenburg, B. (1982)Recl. Trav. Chim. Pays-Bas,101, 1–27.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Crystallography Laboratory, University of Nijmegen, Toernooiveld, 6525, ED Nijmegen, The Netherlands

    R. C. Haltiwanger & Paul T. Beurskens

  2. Department of Organic Chemistry, University of Nijmegen, Toemooiveld, 6525, ED Nijmegen, The Netherlands

    B. Zwanenburg & P. A. T. W. Porskamp

Authors
  1. R. C. Haltiwanger
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Paul T. Beurskens
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. B. Zwanenburg
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. P. A. T. W. Porskamp
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

On leave from the Department of Chemistry, University of Colorado, Boulder, Colorado 80309.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Haltiwanger, R.C., Beurskens, P.T., Zwanenburg, B. et al. Structure and absolute configuration of 10-chloro-10-sulfinylcamphor, C10H13ClO2S. Journal of Crystallographic and Spectroscopic Research 16, 71–78 (1986). https://doi.org/10.1007/BF01566047

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01566047

Keywords

Search

Navigation