Recombination of electrons in a plasma expanding into a vacuum

Abstract

As noted in a paper by one of the authors [1], when a hot ionized gas expands into a vacuum, at a certain moment ionization equilibrium must necessarily break down. Shortly after this point, which may be found by the method indicated in [1], ionizing events become very rare and only recombination occurs in the gas. In [1] photorecombination and triple collisions with the capture of an electro to the ground level of the atom were considered. Here the recombination did not proceed to the end: on expanding to infinity and cooling to zero the gas remained partially ionized.

Papers have recently appeared [2–7] in which the significant role of triple collisions with the capture of electrons to upper atomic levels is noted. The recombination process has a cascade character at low temperatures and densities which are not excessively small. At first, the electron is captured by one of the upper atomic levels in a triple collision with an ion and another electron. Subsequently, as a result of electron collisions of the second kind, and later also as a result of radiative transitions, the bound electron descends through the energy levels to the atomic ground state. The recombination coefficient for such a process depends much more strongly on the electron temperature T than for a triple collision with capture directly by the ground level (as T^−9/2 as opposed to T⁻¹), and at low temperatures cascade recombination proceeds much more quickly than capture to the ground level. Since this casts doubt upon the conclusions of [1] regarding the residual ionization when a plasma expands into a vacuum, we were led to re-examine the question, which, as will be clear from what follows, is not considerably more complicated.