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Compounds of hypercoordinated gold(i)

2. Synthesis and molecular structure of 2,2′-bis(triphenylphosphinegold)diphenylmethane

  • Organometallic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

A binuclear organic derivative of gold(i) with diphenylmethane CH2(C6H4)2(AuPPh3)2 has been prepared by the reaction of 2,2′-dilithiumdiphenylmethane with ClAuPPh3. X-ray analysis of this compound revealed a transoid conformation of the molecule with agostic bonds between the gold atoms and methylene hydrogens. The complex was characterized by IR,1H and31P NMR, and mass spectral data.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Conpounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    T. V. Baukova & N. A. Oleinikova

  2. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 117234, Moscow, Russian Federation

    V. P. Dyadchenko & D. A. Lemenovskii

  3. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation

    L. G. Kuz'mina

Authors
  1. T. V. Baukova
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  2. V. P. Dyadchenko
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  3. N. A. Oleinikova
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  4. D. A. Lemenovskii
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  5. L. G. Kuz'mina
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Additional information

For Report 1 seeRuss. Chem. Bull., 1994,43, 681.

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1125–1130, June, 1994.

This work was performed with partial financial support from the International Science Foundation (Project No. MDV 000).

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Baukova, T.V., Dyadchenko, V.P., Oleinikova, N.A. et al. Compounds of hypercoordinated gold(i). Russ Chem Bull 43, 1063–1068 (1994). https://doi.org/10.1007/BF01558082

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  • DOI: https://doi.org/10.1007/BF01558082

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