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Synthesis, structure and chemical properties of hypervalent germanium compounds, derivatives of lactams with a fragment

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Abstract

The results of studies aimed at elaborating methods for synthesizing penta- and hexacoordinated organogermanium derivatives containing lactamo-N-methyl and related bidentate ligands and investigating their structure and reactivity are reviewed. In these compounds the germanium coordination units include one or two O(or S)-Ge-X or N-Ge-X (X — an electron-deficient group) hypervalent fragments.

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References

  1. S. N. Tandura, M. G. Voronkov, and N. V. Alekseev,Top. Curr. Chem., 1986,131, 99; R. J. P. Corriu,J. Organometal Chem., 1990,400, 81.

    Google Scholar 

  2. V. E. Shklover, Yu. T. Struchkov, and M. G. Voronkov,Usp. Khim., 1989,58, 353 [Russ. Chem. Rev., 1989,58, No 3 (Engl. Transl.)].

    Google Scholar 

  3. M. G. Voronkov, V. A. Pestunovich, and Yu. I. Baukov,Metalloorg. Khim., 1991,4, 1210 [Organomet. Chem. USSR, 1991,4, 593 (Engl. Transl.)].

    Google Scholar 

  4. T. K. Gar, V. F. Mironov,Metalloorg. Khim., 1988,1, 260 [Organomet. Chem. USSR, 1988,1, (Engl. Transl.)].

    Google Scholar 

  5. V. A. Pestunovich, I. D. Kalikhman, Yu. I. Baukov, A. I. Albanov, O. B. Bannikova, L. I. Belousova, E. P. Kramarova, A. G. Shipov, and M. G. Voronkov,Metalloorg. Khim., 1988,1, 719 [Organomet. Chem. USSR, 1988,1, No. 3 (Engl. Transl.)]; I. D. Kalikhman, A. I. Albanov, O. B. Bannikova, L. I. Belousova, S. V. Pestunovich, M. G. Voronkov, V. A. Pestunovich, A. A. Macharashvili, V. E. Shklover, Yu. T. Struckov, T. I. Khaustova, G. Ya. Zueva, E. P. Kramarova, A. G. Shipov, G. I. Oleneva, and Yu. I. Baukov,Metalloorg. Khim., 1989,2, 637 [Organomet. Chem. USSR, 1989,2, 326 (Engl. Transl.)].

    Google Scholar 

  6. I. D. Kalikhman, A. I. Albanov, O. B. Bannikova, L. I. Belousova, M. G. Voronkov, V. A. Pestunovich, A. G. Shipov, E. P. Kramarova, and Yu. I. Baukov,J. Organometal. Chem., 1989,361, 147.

    Google Scholar 

  7. J. Kowalski and Z. Lasocki,J. Organometal. Chem., 1976,116, 75.

    Google Scholar 

  8. K. D. Onan, A. T. McPhail, C. H. Yoder, and R. W. Hillyard,J. Chem. Soc., Chem. Commun., 1978, 209.

  9. R. W. Hillyard, C. M. Ryan, and C. H. Yoder,J. Organometal. Chem., 1978,153, 369; C. H. Yoder, C. M. Ryan, G. F. Martin, and P. S. Ho,J. Organometal. Chem., 1980,190, 1.

    Google Scholar 

  10. V. D. Sheludyakov, N. I. Kirilina, M. G. Kuznetsova, A. V. Kisin, and A. D. Kirilin,Zh. Obshch. Khim., 1981,51, 1824 [J. Gen. Chem. USSR, 1981,51 (Engl. Transl.)]; V. D. Sheludyakov, Ya. M. Paushkin, N. I. Kirilina, and A. D. Kirilin,Dokl. Akad. Nauk SSSR, 1979,246, 1152 [Dokl. Chem., 1979,246 (Engl. Transl.)]; V. D. Sheludyakov, N. I. Kirilina, Ya. M. Paushkin, and A. D. Kirilin,Dokl. Akad. Nauk SSSR, 1980,254, 1412 [Dokl. Chem., 1980,254 (Engl. Transl.)]; V. D. Sheludyakov, N. I. Kirilina, E. L. Kotrikadze, A. D. Kirilin, and E. A. Chernyshev,Zh. Obshch. Khim., 1982,52, 2646 (J. Gen. Chem. USSR, 1982,52 (Engl. Transl.)]; V. D. Sheludyakov, N. I. Kirilina, and A. D. Kirilin,Zh. Obshch. Khim., 1983,53, 469 [J. Gen. Chem. USSR, 1983,53 (Engl. Transl.)]; V. D. Sheludyakov, E. L. Kotrikadze, and A. D. Kirilin,Zh. Obshch. Khim., 1984,54, 1134 [J. Gen. Chem. USSR, 1984,54 (Engl. Transl.)].

    Google Scholar 

  11. K. Shitara and Y. Sato,J. Organometal. Chem., 1988,436, 1.

    Google Scholar 

  12. Yu. I. Baukov, E. P. Kramarova, A. G. Shipov, G. I. Oleneva, O. B. Artamkina, A. I. Albanov, M. G. Voronkov, and V. A. Pestunovich,Zh. Obshch. Khim., 1989,59, 127 [J. Gen. Chem. USSR, 1989,59 (Engl. Transl.)].

    Google Scholar 

  13. A. O. Mozzchukhin, A. A. Macharashvili, V. E. Shklover, Yu. T. Struckov, A. G. Shipov, V. N. Sergeev, S. A. Artamkin, S. V. Pestunovich, and Yu. I. Baukov,J. Organometal. Chem., 1991,408, 305.

    Google Scholar 

  14. E. P. Kramarova, G. I. Oleneva, A. G. Shipov, T. I. Khaustova, G. Ya. Zueva, and Yu. I. Baukov,Metalloorg. Khim., 1991,4, 468 [Organomet. Chem. USSR, 1991,4, No. 2 (Engl. Transl.)].

    Google Scholar 

  15. V. F. Sidorkin, V. A. Pestunovich, G. K. Balakhchi, and M. G. Voronkov,Izv. Akad. Nauk SSSR, Ser. Khim., 1985, 622 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1985,34, 568 (Engl. Transl.)].

    Google Scholar 

  16. A. A. Macharashvili, V. E. Shklover, Yu. T. Struchkov, G. I. Oleneva, E. P. Kramarova, A. G. Shipov, and Yu. I. Baukov,J. Chem. Soc. Chem. Commun., 1988, 683; A. A. Macharashvili, Thesis for the degree of Candidate of Chemical Sciences, INEOS RAN, Moscow, 1990.

  17. S. N. Gurkova, A. I. Gusev, N. V. Alexeev, O. A. Dombrova, and T. K. Gar,Metalloorg. Khim., 1991,4, 611 [Organomet. Chem. USSR, 1991,4 (Engl. Transl.)].

    Google Scholar 

  18. S. N. Gurkova, A. I. Gusev, N. V. Alexeev, T. K. Gar, and N. A. Viktorov,Zh. Strukt. Khim., 1984,25, 170 [J. Struct. Chem., 1984,25 (Engl. Transl.)].

    Google Scholar 

  19. S. N. Gurkova, A. I. Gusev, N. V. Alexeev, T. K. Gar, and N. A. Viktorov,Zh. Strukt. Khim., 1985,26, 144 [J. Struct. Chem., 1986,26 (Engl. Transl.)].

    Google Scholar 

  20. A. O. Mozzchukhin, M. Yu. Antipin, Yu. T. Struchkov, A. G. Shipov, E. P. Kramarova, and Yu. I. Baukov,Metalloorg. Khim., 1992,5, 906 [Organomet. Chem. USSR, 1992.5 (Engl. Transl.)].

    Google Scholar 

  21. E. P. Kramarova, A. G. Shipov, L. S. Smirnova, O. B. Artamkina, Yu. I. Baukov, A. O. Mozzchukhin, Yu. E. Ovchinnikov, and Yu. T. Struckov,Zh. Obshch. Khim., 1993,63, 2275 [J. Gen. Chem. USSR, 1993,63 (Engl. Transl.)].

    Google Scholar 

  22. E. P. Kramarova, A. G. Shipov, T. I. Khaustova, G. Ya. Zueva, and Yu. I. Baukov,Zh. Obshch. Khim., 1992,62, 2156 [J. Gen. Chem. USSR, 1992,62 (Engl. Transl.)].

    Google Scholar 

  23. A. G. Shipov, E. P. Kramarova, O. B. Artamkina, and Yu. I. Baukov,Metalloorg. Khim., 1991,4, 1101 [Organomet. Chem. USSR, 1991,4 (Engl. Transl.)].

    Google Scholar 

  24. N. A. Orlova, A. G. Shipov, Yu. I. Baukov, A. O. Mozzchukhin, M. Yu. Antipin, and Yu. T. Struckov,Metalloorg. Khim., 1992,5, 666 [Organomet. Chem. USSR, 1992,5 (Engl. Transl.)].

    Google Scholar 

  25. A. G. Shipov, E. P. Kramarova, S. Yu. Bylikin, E. A. Mamaeva, G. S. Zaitseva, V. N. Sergeev, and Yu. I. Baukov,Zh. Obshch. Khim., 1993,63, 1195 [J. Gen. Chem. USSR, 1993,63 (Engl. Transl.)].

    Google Scholar 

  26. M. G. Voronkov, A. I. Albanov, V. N. Sergeev, S. V. Pestunovich, Ya. Ya. Kandror, and Yu. I. Baukov,Metalloorg. Khim., 1988,1, 1435 [Organomet. Chem. USSR, 1988,1, No 6 (Engl. Transl.)].

    Google Scholar 

  27. A. A. Macharashvili, Yu. E. Ovchinnikov, Yu. T. Struckov, V. N. Sergeev, S. V. Pestunovich, and Yu. I. Baukov,Izv. Akad. Nauk, Ser. Khim., 1993, 189 [Russ. Chem. Bull., 1993,42 (Engl. Transl.)].

    Google Scholar 

  28. M. S. Sorokin, S. G. Shevchenko, N. N. Chipanina, Yu. L. Frolov, M. F. Larin, and M. G. Voronkov,Metalloorg. Khim., 1990,3, 419 [Organomet. Chem. USSR, 1990,3 (Engl. Transl.)].

    Google Scholar 

  29. Yu. E. Ovchinnikov, M. S. Sorokin, Yu. T. Struckov, and M. G. Voronkov,Dokl. Akad. Nauk SSSR, 1993,330, 337 [Dokl. Chem., 1993,330 (Engl. Transl.)].

    Google Scholar 

  30. S. A. Artamkin, V. N. Sergeev, Yu. I. Baukov, A. O. Mozzchukhin, M. Yu. Antipin, and Yu. T. Struckov,Metalloorg. Khim., 1991,4, 1024 [Organomet. Chem. USSR, 1991.4, 500 (Engl. Transl.)].

    Google Scholar 

  31. E. P. Kramarova, A. G. Shipov, G. I. Oleneva, and Yu. I. Baukov,Zh. Obshch. Khim., 1991,61, 1918 [J. Gen. Chem. USSR, 1991,61 (Engl. Transl.)].

    Google Scholar 

  32. E. P. Kramarova, A. G. Shipov, G. I. Oleneva, Yu. I. Baukov, A. O. Mozzchukhin, M. Yu. Antipin, and Yu. T. Struckov,Metalloorg. Khim., 1991,4, 1016 [Organomet. Chem. USSR, 1991,4, 496 (Engl. Transl.)].

    Google Scholar 

  33. Yu. I. Baukov, A. G. Shipov, L. S. Smirnova, E. P. Kramarova, S. Yu. Bylikin, Yu. E. Ovchinnikov, and Yu. T. Struchkov,J. Organometal. Chem., 1993,461, 39.

    Google Scholar 

  34. Yu. E. Ovchinnikov, Yu. T. Struckov, Yu. I. Baukov, A. G. Shipov, and S. Yu. Bylikin,Izv. Akad. Nauk, Ser. Khim., 1994, 1427 [Russ. Chem. Bull., 1994,43 (Engl. Transl.)].

    Google Scholar 

  35. Yu. E. Ovchinnikov, Yu. T. Struckov, Yu. I. Baukov, A. G. Shipov, E. P. Kramarova, and S. Yu. Bylikin,Izv. Akad. Nauk, Ser. Khim., 1994, 1421 [Russ. Chem. Bull., 1994,43 (Engl. Transl.)].

    Google Scholar 

  36. C. Chuit, R. Corriu, A. Mehdi, and C. Reye,Xth International Symposium on Organosilicon Chemistry, August 15–20, 1993, Poznan, Poland, 1993, 246.

  37. F. Carre, C. Chuit, R. Corriu, A. Mehdi, and C. Reye,Xth International Symposium on Organosilicon Chemistry, August 15–20, 1993, Poznan, Poland, 1993, 245.

  38. R. Probst, C. Lewis, S. Gampra, E. Herdtweck, C. Zybill, and N. Auner,Angew. Chem. Int. Ed. Engl., 1991,103, 1132; H. Handwerker, C. Leis, R. Probst, P. Bissinger, A. Grohmann, P. Kiprof, E. Herdtweck, J. Blumel, N. Auner, and C. Zybill,Organometallics, 1993,12, 2162.

    Google Scholar 

  39. I. D. Kalikhman, O. B. Bannikova, B. A. Gostevskii, O. A. Vyazankina, N. S. Vyazankin, and V. A. Pestunivich,Izv. Akad. Nauk SSSR, Ser. Khim., 1985, 1688 [Bull. Akad. Sci. USSR, Div. Chem. Sci., 1985,34, 1547 (Engl. Transl.)]; I. D. Kalikhman, O. B. Bannikova, L. I. Belousova, B. A. Gostevskii, E. Liepin'sh, O. A. Vyazankina, N. S. Vyazankin, and V. A. Pestunovich,Metalloorg. Khim., 1988,1, 683 [Organomet. Chem. USSR, 1988,1, No. 3 (Engl. Transl.)].

  40. A. R. Bassindale, T. Stout,J. Organometal. Chem., 1983,238, C41.

    Google Scholar 

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Authors and Affiliations

  1. Russian State Medical University, 1 ul. Ostrovityanova, 117869, Moscow, Russian Federation

    Yu. I. Baukov & A. G. Shipov

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    Yu. E. Ovchinnikov & Yu. T. Struchkov

Authors
  1. Yu. I. Baukov
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  2. A. G. Shipov
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  3. Yu. E. Ovchinnikov
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  4. Yu. T. Struchkov
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Additional information

The review is based on the report at the conference “Workshop on the Modern Problems of Heteroorganic Chemistry”, Moscow, May 8–13, 1993.

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 982–993, June, 1994.

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Baukov, Y.I., Shipov, A.G., Ovchinnikov, Y.E. et al. Synthesis, structure and chemical properties of hypervalent germanium compounds, derivatives of lactams with a fragment. Russ Chem Bull 43, 917–928 (1994). https://doi.org/10.1007/BF01558048

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