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Synthesis and the crystal and molecular structure of the germanium(IV) complex with propylene-1,3-diaminetetraacetic acid [Ge(Pdta)]

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Abstract

The germanium(IV) complex with propylene-1,3-diaminetetraacetic acid (H4 Pdta) is studied by elemental analysis, X-ray diffraction, thermogravimetry, and IR spectroscopy. The X-ray diffraction study reveals two crystallographically independent [Ge(Pdta)] molecules of similar structure. Both Ge atoms are octahedrally coordinated by four O atoms and two N atoms (at the cis positions) of the hexadentate pentachelate Pdta 4– ligand. An extended system of weak С—Н···О hydrogen bonds connects complex molecules into a supramolecular 3D framework.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    V. S. Sergienko & A. V. Churakov

  2. Odessa National University, ul. Dvoryanskaya 2, Odessa, 65082, Ukraine

    E. E. Martsinko, I. I. Seifullina & E. A. Chebanenko

Authors
  1. V. S. Sergienko
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  2. E. E. Martsinko
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  3. I. I. Seifullina
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  4. A. V. Churakov
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  5. E. A. Chebanenko
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Corresponding author

Correspondence to V. S. Sergienko.

Additional information

Original Russian Text © V.S. Sergienko, E.E. Martsinko, I.I. Seifullina, A.V. Churakov, E.A. Chebanenko, 2015, published in Kristallografiya, 2015, Vol. 60, No. 5, pp. 740–744.

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Sergienko, V.S., Martsinko, E.E., Seifullina, I.I. et al. Synthesis and the crystal and molecular structure of the germanium(IV) complex with propylene-1,3-diaminetetraacetic acid [Ge(Pdta)]. Crystallogr. Rep. 60, 677–681 (2015). https://doi.org/10.1134/S1063774515040197

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  • DOI: https://doi.org/10.1134/S1063774515040197

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