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The determination of the molecular weight and interactions of a polyelectrolyte in aqueous salt solutions by light scattering

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Summary

The light scattering results for a polyelectrolyte in a binary solvent are experimentally evaluated in terms of the theory for multicomponent systems developped independently by Kirkwood and Stockmayer. Two proven experimental methods for molecular weight determination are discussed.

Zusammenfassung

Die Ergebnisse der Lichtstreuung für Polyelektrolyte in einem zweiwertigen Lösungsmittel werden experimentell mit der Theorie für Mehrkomponentensysteme ausgewertet, wie sie unabhängig voneinander Kirkwood und Stockmayer entwickelt haben. Zwei experimentelle Methoden für Molekulargewichtsbestimmung werden diskutiert.

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References

  1. Ewart, R. H., C. P. Roe, P. Debye and McCartney, J. Chem. Phys. 14, 687 (1946).

    Article  CAS  Google Scholar 

  2. Mysels, K. J., J. Phys. Chem. 58, 303 (1954).

    Article  CAS  Google Scholar 

  3. Brinkman, H. C. and J. J. Hermans, Chem. Phys. 17, 574 (1949).

    Article  CAS  Google Scholar 

  4. Kirkwood, J. G. and R. J. Goldberg, J. Chem. Phys. 18, 54 (1950).

    Article  CAS  Google Scholar 

  5. Stockmayer, W. H., J. Chem. Phys. 18, 58 (1950).

    Article  CAS  Google Scholar 

  6. Ehrlich, G., J. Phys. Chem. 58, 769 (1954).

    Google Scholar 

  7. Casassa, E. F., J. Phys. Chem. 60, 926 (1956).

    Article  CAS  Google Scholar 

  8. Strauss, U. P. and P. L. Wineman, J. Amer. Chem. Soc. 80, 2366 (1958).

    Article  CAS  Google Scholar 

  9. Ander, P., Ph. D. Thesis (Rutgers, The State University, 1961, New Brunswick, N. J.).

    Google Scholar 

  10. Scatchard, G., J. Amer. Chem. Soc. 68, 2315 (1946).

    Article  CAS  Google Scholar 

  11. Strauss, U. P. and P. Ander, J. Amer. Chem. Soc. 80, 6494 (1958).

    Article  CAS  Google Scholar 

  12. Casassa, E. F. and H. Eisenberg, J. Amer. Chem. Soc. 64, 753 (1960).

    CAS  Google Scholar 

  13. Eisenberg, H. and E. F. Casassa, J. Polymer Sci. 47, 29 (1960).

    Article  CAS  Google Scholar 

  14. Doty, P. and B. A. Bunce, J. Amer. Chem. Soc. 74, 5029 (1952).

    Article  CAS  Google Scholar 

  15. Bluestone, S., Ph. D. Thesis (Rutgers, The State University, 1961, New Brunswick, N. J.).

    Google Scholar 

  16. Ise, N. and U. P. Strauss (Private communication).

  17. Edsall, J. T., H. Edelhoch, R. Lontie, and P. R. Morrison, J. Amer. Chem. Soc. 72, 4641 (1950).

    Article  CAS  Google Scholar 

  18. Doty, P. and J. T. Edsall, Advances in Protein Chemistry, Vol. VI, p. 35 (New York, N. Y., 1951).

    Article  Google Scholar 

  19. Scatchard, G. and J. Bregman, J. Amer. Chem. Soc. 81, 6095 (1959).

    Article  CAS  Google Scholar 

  20. Stigter, D., J. Phys. Chem. 64, 842 (1960).

    CAS  Google Scholar 

  21. Vrij, A., Thesis (Utrecht 1959).

Download references

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Ander, P. The determination of the molecular weight and interactions of a polyelectrolyte in aqueous salt solutions by light scattering. Kolloid-Z.u.Z.Polymere 185, 102–105 (1962). https://doi.org/10.1007/BF01542344

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  • DOI: https://doi.org/10.1007/BF01542344

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