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Reactivity of acrylic monomers

I. Copolymerization of N,N-diethylacrylamide with methyl acrylate

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Summary

The copolymerization of N,N-diethylacrylamide (Ml) with methyl acrylate (M2) was investigated and reactivity ratiosr 1= 0.41 andr 2 = 0.52 obtained. Also the distribution of diad fractions was calculated and the results were interpreted in terms of the product of reactivity ratios. The tendency of the two monomers to alternate was explained on the basis of differences in polatities between the double bonds, this explanation being supported both by the values ofe parameter and NMR spectroscopy data. A copolymerization mechanism was suggested.

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References

  1. Azuma, C., N. Ogate, J. Polym. Sci., Chem. Ed.13, 741 (1975).

    Google Scholar 

  2. Kopecek, J., H. Barilova, Eur. Polym. J.9, 7 (l973).

    Google Scholar 

  3. Takazuki, O., Y. Bunichiro, J. Masaki, M. Takashi, J. Polym. Sci., Chew. Ed.14, 1347 (1976).

    Google Scholar 

  4. Ulbrich, K., J. Kopecek, Collect. Czech. Chem. Comun.41, 61 (l976).

    Google Scholar 

  5. Ulbrich, K., J. Kopecek, Eut. Polym. J.12, 1831 (1976).

    Google Scholar 

  6. Takazuki, O., J. Masami, Kobunshi Renbunshi31, 250 (1974), Chem. Abstr.83, 59406 cl.

    Google Scholar 

  7. Mihes, F., Eut. Polym. J.10, 1029 (1974).

    Google Scholar 

  8. Strohalm, J., K. Ulbrich, J. Exner, J. Kopecek, Angew. Makromol. Chem.89, 83 (1976).

    Google Scholar 

  9. Pauzic, H. L., J. E. Mulraney, J. Polym. Sci., Chem. Ed. 10, 3469 (l972).

    Google Scholar 

  10. Izhak, B., F. Joseph, Get. Offen, 2, 446, 449 (1975).

  11. Koester, H., W. Heidman, Angew. Makromol. Chem.88, 576 (1976).

    Google Scholar 

  12. Stampel, G. H., R. P. Cross, J. Amer. Chem. Soc.72, 2299 (1950).

    Google Scholar 

  13. Mullier, M., G. Smets, J. Polym. Sci.23, 915 (1957).

    Google Scholar 

  14. Burtk, J. G., Anal. Chem.27, 1215 (1955).

    Google Scholar 

  15. Ma, T. S., G. Zazuga, Ind. Eng. Chem. Analyst.14, 280 (1942).

    Google Scholar 

  16. Mayo, F. R., F. M. Lewis, Ind. Eng. Chem. Anal. Ed.17, 134 (1945).

    Google Scholar 

  17. Fineman, M., S. D. Ross, J. Polym. Sci.5, 259 (1950).

    Google Scholar 

  18. Greenley, R. Z., J. Macromol. Sci. Chem.A9, (4), 505 (1975).

    Google Scholar 

  19. North, A., A. Scallen, Polymer5, 447 (l964).

    Google Scholar 

  20. Harwood, H. J., W. H. Ritchey, J. Polym. Sci.B2, 601 (1964).

    Google Scholar 

  21. Hatada, K., K. Nagate, H. Yuki, Bull. Chem. Soc. Jap.43, 3267 (1970).

    Google Scholar 

  22. Mayo, F. R., F. M. Lewis, C. Walling, J. Amer. Chem. Soc.70, 1529 (1948).

    Google Scholar 

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Authors and Affiliations

  1. Department of Organic Chemistry Faculty of Chemical Technology, Bahlui Stînga Street 7, Jassy, Rumania

    E. Dumitriu, Sp. Oprea, S. Maxim, A. Nathanson & M. Dima

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  1. E. Dumitriu
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  2. Sp. Oprea
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  3. S. Maxim
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  4. A. Nathanson
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  5. M. Dima
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With 5 figures and 2 tables

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Dumitriu, E., Oprea, S., Maxim, S. et al. Reactivity of acrylic monomers. Colloid & Polymer Sci 257, 1203–1206 (1979). https://doi.org/10.1007/BF01517245

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  • DOI: https://doi.org/10.1007/BF01517245

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