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Reinforcement by carbon black considered as a rate process

Part I: The mechanics of single macromolecules under tension

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Summary

Following a survey of the behaviour of elastomers loaded with carbon black, a mechanism of reinforcement is proposed which is based upon theDannenberg's concept of “mobile absorption” or “molecular slippage” of elastomer macromolecules on the carbon black surface, and treats their motion as a rate process. The behaviour of single molecular chains is described in detail.

Zusammenfassung

Aus einer kritischen Betrachtung des Verhaltens rußgefüllter Elastomerer wurde ein Mechanismus für die Verstärkung vorgeschlagen, demDannenberg's Konzept der „mobilen Adsorption“ oder „molekularen Gleitung“ der Elastomer-Makromoleküle auf der Rußoberfläche zugrundeliegt. Ihre Bewegung wurde kinetisch behandelt. Das Verhalten einzelner Molekülketten wird im Detail beschrieben.

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Author notes

  1. Z. Rigbi (Technion)

    Present address: Haifa Institute of Technology, Haifa, Israel

Authors and Affiliations

  1. Cabot Corporation, Cambridge, Mass., USA

    Z. Rigbi (Technion)

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  1. Z. Rigbi
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Rigbi, Z. Reinforcement by carbon black considered as a rate process. Kolloid-Z.u.Z.Polymere 223, 127–134 (1968). https://doi.org/10.1007/BF01500508

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  • DOI: https://doi.org/10.1007/BF01500508

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