Skip to main content
SpringerLink
Log in

On precipitation effects of aluminum, lanthanum, iron (III), and thorium phosphates

  • Originalarbeiten
  • Kolloide und Natürliche Makromoleküle
  • Published:
Kolloid-Zeitschrift und Zeitschrift für Polymere Aims and scope Submit manuscript

Summary

Typical precipitation curves of various metal phosphates have been obtained using the turbidimetric technique. The following systems have been investigated: Al(NO3)3-K3PO4, Al(NO3)3-KH2PO4, Al(NO3)3NaH2PO4, FeCl3-K3PO4, FeCl3-(NH4)2HPO4, FeCl3K2HPO4, FeCl3-KH2PO4, FeCl3-NaH2PO4, La(NO3)3K3PO4,La(NO3)3-K2HPO4,La(NO3)3-KH2PO4,La(NO3)3NaH2PO4 and Th(NO3)4-K2HPO4. Typical precipitation curves indicated concentration ranges of phosphate precipitation and of complex solubility.

Zusammenfassung

Typische Fällungskurven verschiedener Metallphosphate, die mittels Trübungsmessungen erhalten wurden, wurden graphisch dargestellt. Die folgenden Systeme wurden untersucht: Al(NO3)3-K3PO4,Al(NO3)3KH2PO4, Al(NO3)3-NaH2PO4, FeCl3-K3PO4, FeCl3(NH4)2HPO4, FeCl3-K2HPO4, FeCl3-KH2PO4, FeCl3NaH2PO4, La(NO3)3-K3PO4, La(NO3)3-K2HPO4, La(NO3)3-KH2PO4, La(NO3)3-NaH2PO4 und Th(NO3)4K2HPO4. Typische Fällungskurven zeigten Konzentrationsgebiete, in welchen die Metallphosphate gefällt werden, sowie Konzentrationen, die zur Komplexbildung führten.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Težak, B., Arhiv kem.19, 19 (1947).

    Google Scholar 

  2. Matijević, E. andB. Težak, Kolloid-Z.136, 74 (1954).

    Article  Google Scholar 

  3. Matijević, E. andN. Pavković, Kolloid-Z.159, 1 (1958).

    Article  Google Scholar 

  4. Kratochvil, J. P., B. Težak, andV. B. Vouk, Arhiv kem.26, 191 (1954).

    Google Scholar 

  5. Schulz, K. F., E. Matijević, andM. Kerker, J. Chem. Eng. Data6, 333 (1961).

    Article  CAS  Google Scholar 

  6. Težak, B., E. Matijević, andK. Schulz, J. Phys. Chem.55, 1557 (1951).

    Article  Google Scholar 

  7. Matijević, E., J. P. Kratohvil, andM. Kerker, J. Chem. Educ.38, 348 (1960).

    Google Scholar 

  8. Sauer, H., Z. techn. Physik12, 148 (1931).

    CAS  Google Scholar 

  9. Krleža, F., Kolloid-Z.169, 131 (1960).

    Article  Google Scholar 

  10. Brosheer, J. C., F. A. Lenfesty, andJ. F. Anderson, Jr., J. Amer. Chem. Soc.76, 5951 (1954).

    Article  CAS  Google Scholar 

  11. Jameson, R. F. andJ. E. Salmon, J. Chem. Soc.1954, 4013.

  12. Hubicki, W. andJ. Mazurek, Ann. Univ. Mariae Curie-Sklodowska, Lublin-Polonia, Sect. AA,2, 69 (1947).

    CAS  Google Scholar 

  13. Rathje, W., Ber.74, 357 (1941);74, B 546 (1941).

    Google Scholar 

  14. Travers, M. and Mlle.Perron, Ann. Chim. [10],1, 298 (1924).

    Google Scholar 

  15. Cole, C. V. andM. L. Jackson, J. Phys. Chem.54, 128 (1950).

    Article  CAS  Google Scholar 

  16. Swenson, R. M., C. V. Cole, andD. H. Sieling, Soil Sci.67, 3 (1949).

    Article  CAS  Google Scholar 

  17. Ensminger, L. E., Soil Sci. Soc. Amer. Proc.13, 170 (1948).

    Article  Google Scholar 

  18. Svanberg, O., Z. anorg. allgem. Chem.108, 70 (1919).

    Article  CAS  Google Scholar 

  19. Dede, L., Z. anorg. allgem. Chem.125, 28 (1923).

    Article  CAS  Google Scholar 

  20. Bjerrum, N. andC. R. Dahm, Z. physik. Chem.Bodenstein-Festband1931, 627.

  21. Matijević, E., K. G. Mathai, R. H. Ottewill, andM. Kerker, J. Phys. Chem.65, 826 (1961).

    Google Scholar 

  22. Rathje, W., Ber.74, 357, 546 (1941).

    Google Scholar 

  23. Bachelet, M. andP. Mouret, Bull. soc. chim. France1948, 268.

  24. Cloutier, L., Ann. Chim.19, 5 (1933).

    CAS  Google Scholar 

  25. Hubicki, W. andK. Sykut, Ann. Univ. Mariae Curie-Sklodowska, Lublin-Polonia, Sect. AA,2, No. 10, 167 (1947).

    CAS  Google Scholar 

  26. Jameson, R. F. andJ. E. Salmon, J. Chem. Soc.1954, 28.

  27. Težak, B. andR. Wolf, Arhiv kem.25, 39 (1953).

    Google Scholar 

  28. Dede, L., Z. anorg. allgem. Chem.125, 28 (1923).

    Article  CAS  Google Scholar 

  29. Ricca, B. andP. Meduri, Gazz. chim. ital.64, 235 (1934).

    CAS  Google Scholar 

  30. Jense, K. A., Z. anorg. allgem. Chem.221, 1 (1934).

    Article  Google Scholar 

  31. Lanford, O. E. andS. J. Kiehl, J. Amer. Chem. Soc.64, 291 (1942).

    Article  CAS  Google Scholar 

  32. Salmon, J. E., J. Chem. Soc.1952, 2317.

  33. Weinland, R. F. andF. Ensgraber, Z. anorg. allgem. Chem.84, 340 (1914).

    CAS  Google Scholar 

  34. Salmon, J. E., J. Chem. Soc.1953, 2644.

  35. Genge, J. A. R. andJ. E. Salmon, J. Chem. Soc.1959, 1495.

  36. Sillèn, L. G., Quart. Revs. (London)13, 146 (1959).

    Google Scholar 

  37. Sykes, K. W., J. Chem. Soc.1959, 2473.

  38. Matijević, E. andB. Težak, Kolloid-Z.146, 65 (1956).

    Article  Google Scholar 

  39. Buyers, A. G., E. Giesbrecht andL. F. Audrieth, J. Inorg. Nucl. Chem.5, 133 (1957).

    Article  CAS  Google Scholar 

  40. Hubicki, W., Ann. Univ. Mariae Curie-Sklodowska Lublin-Polonia, Sect. AA,2, 185 (1947).

    CAS  Google Scholar 

  41. Matijević, E., M. B. Abramson, K. F. Schulz andM. Kerker, J. Phys. Chem.64, 1157 (1960).

    Google Scholar 

  42. Castel, P., Compt. rend.208, 519 (1939).

    CAS  Google Scholar 

  43. D'Ans, J. andW. Dawihl, Z. anorg. allgem. Chem.178, 252 (1929).

    Article  Google Scholar 

  44. Oka, Y., J. Chem. Soc. Japan61, 311 (1940).

    CAS  Google Scholar 

  45. Korenman, I. M., Zhur. Obshchei Khim.25, 1801 (1955).

    CAS  Google Scholar 

  46. Zabroski, E. L., H. W. Alter, andF. K. Heumann, J. Amer. Chem. Soc.73, 5646 (1951).

    Article  Google Scholar 

Download references

Author information

Author notes

  1. E. Matijević

    Present address: Clarkson College of Technology, Potsdam, N. Y., USA

  2. I. Milić

    Present address: Laboratory of Physical Chemistry, Faculty of Science, University of Zagreb, Zagreb, Croatia (Yugoslavia)

Authors and Affiliations

  1. Clarkson College of Technology, Potsdam, N. Y., USA

    I. Milić

  2. Laboratory of Physical Chemistry, Faculty of Science, University of Zagreb, Zagreb, Croatia (Yugoslavia)

    E. Matijević

Authors
  1. E. Matijević
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. Milić
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Supported in part by the U.S. Army Research Office, Contract No. DA-ORD-10.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Matijević, E., Milić, I. On precipitation effects of aluminum, lanthanum, iron (III), and thorium phosphates. Kolloid-Z.u.Z.Polymere 188, 129–136 (1963). https://doi.org/10.1007/BF01499905

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01499905

Keywords

Search

Navigation