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Determination of configuration of products of nucleophilic addition to activated acetylenes by the NMR method

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

It was shown that the stereospecificity of SSCC3 transC,H > 3J cisC,H is applicable as a configurational test for di- and trisubstituted alkenes R2E(Y)C=C(X)H with various heteroatomic substituents (E=N, P, S) and activating groups (X=CO2Alk, CN at Y=H, and X=Y=CO2Alk, CN, CF3).

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    N. L. Zaichenko, I. I. Chervin, V. N. Voznesenskii, Yu. I. Él'natanov & R. G. Kostyanovskii

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  1. N. L. Zaichenko
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  2. I. I. Chervin
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  3. V. N. Voznesenskii
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  4. Yu. I. Él'natanov
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  5. R. G. Kostyanovskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 779–783, April, 1988.

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Zaichenko, N.L., Chervin, I.I., Voznesenskii, V.N. et al. Determination of configuration of products of nucleophilic addition to activated acetylenes by the NMR method. Russ Chem Bull 37, 663–666 (1988). https://doi.org/10.1007/BF01455472

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  • DOI: https://doi.org/10.1007/BF01455472

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