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The effect of polyoxyethylene glycol monoethers ofn-hexadecanol on the stability of a polystyrene latex dispersion

  • Colloid Science
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Abstract

The influence of nonionic surface active agents, a series of polyoxyethylene glycol monoethers ofn-hexadecanol, on the stability of dispersions of 2μm diameter polystyrene latices has been investigated.

Adsorption and microelectrophoretic studies showed the presence of looped monolayers of surface active agent at plateau adsorption.

Examination of sedimentation volumes and redispersibility, correlated with potential energy calculations, showed that the stability of the dispersions depended on the characteristics of the adsorbed layer and on added electrolyte.

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References

  1. Mathai, K. G., R. H. Ottewill, Colloid Z., Z. Polym.185, 55 (1962)

    Article  CAS  Google Scholar 

  2. Mathai, K. G., R. H. Ottewill, Trans. Faraday Soc.62, 750 (1966).

    Article  CAS  Google Scholar 

  3. Mathai, K. G., R. H. Ottewill, Trans. Faraday Soc.62, 759 (1966)

    Article  CAS  Google Scholar 

  4. Ottewill, R. H., T. Walker, Kolloid Z.227, 108 (1968).

    Article  CAS  Google Scholar 

  5. Ottewill, R. H., T. Walker, J. Chem. Soc. Faraday Trans. I70, 917 (1974).

    Article  Google Scholar 

  6. Kayes, J. B., J. Colloid & Interface Sci.56, 426 (1976).

    Article  CAS  Google Scholar 

  7. Elworthy, P. H., W. G. Guthrie, J. Pharm. Pharmac.22, 1145 (1970).

    Article  Google Scholar 

  8. Chung-Li, Y., J. W. Goodwin, R. H. Ottewill, Progr. Colloid & Polym. Sci.60, 163 (1976).

    Article  CAS  Google Scholar 

  9. Ross, S., J. P. Oliver, J. Phys. Chem.63, 1671 (1959).

    Article  CAS  Google Scholar 

  10. Matthews, B. A., C. T. Rhodes, J. Pharm. Sci.57, 569 (1968).

    Article  CAS  Google Scholar 

  11. Kayes, J. B., D. A. Rawlins, Colloid & Polymer Sci.257, 622 (1979).

    Article  CAS  Google Scholar 

  12. Ottewill, R. H., in: “Nonionic Surfactants” M. J. Shick, ed. Arnold (London 1967).

    Google Scholar 

  13. Wiese, G. R., T. W. Healy, J. Colloid & Interface Sci.51, 434 (1975).

    Article  CAS  Google Scholar 

  14. Stumm, W., J. J. Morgan, J. Am. Water Works Assoc.54, 971 (1962).

    CAS  Google Scholar 

  15. Vincent, B., J. Colloid & Interface Sci.42, 270 (1973).

    Article  CAS  Google Scholar 

  16. Rawlins, D. A., Ph. D. Thesis, University of Aston (1979).

  17. Overbeek, J. Th. G., p. 130, Colloid Science Vol I, Kruyt, H. R. (Ed) Elsevier 1949.

  18. Hiestand, E. N., J. Pharm. Sci.61, 268 (1972).

    Article  CAS  Google Scholar 

  19. Schenkel, J. H., J. A. Kitchener, Trans. Faraday Soc.56, 161 (1960).

    Article  CAS  Google Scholar 

  20. Rawlins, D. A., J. B. Kayes, Drug Dev. Ind. Pharm.6, (5), 427 (1980).

    Article  CAS  Google Scholar 

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Law, S.L., Kayes, J.B. The effect of polyoxyethylene glycol monoethers ofn-hexadecanol on the stability of a polystyrene latex dispersion. Colloid & Polymer Sci 260, 326–332 (1982). https://doi.org/10.1007/BF01447972

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  • DOI: https://doi.org/10.1007/BF01447972

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