Abstract
An automated expansion apparatus has been set up which can be used for PVT measurements on gases from Il to 60 C at pressures from 2 to 7 NIPa. It consists of two chambers connected by an expansion valve. The ratio of the two volumes is 1:54. The measurements along one isotherm. which take 20 h, can be per formed routinely and without operator attendance. The uncertainty of the com pressibility factor is estimated to be 10−3. The compressibility factors of binary mixtures of the main components of most natural gases, methane and ethane, were determined on high-grade gas, the mole fractions of ethane being 0.05, 0.15. and 0.25. Seven isotherms were measured of each of the mixtures. Data from the literature for the virial coefficients of the pure substances were used to establish a virial equation of state which approximates the measured com pressibility factors with a standard deviation of 0.4 x 10 '. This is substantially smaller than the uncertainty. The interaction virial coefficients were calculated from this equation of state. The results obtained are in good agreement with other available data.
Similar content being viewed by others
References
W. Blanke and R. Weiss,PTB-Mitt. 99:357 (1989).
N. Pieperbeck, R. Kleinrahm, W. Wagner, and M. Jaeschke,J. Chem. Thermodyn. 23;175 (1991).
J. H. Dymond and E. B. Smith,The Virial Coefficients of Pure Gases und Mixtures (Clarendon Press, Oxford, 1980), pp. 35–42, 74–80.
M. Jaeschke, S. Audibert, P. van Caneghem, A.E. Humphreys. R. Janssen-van Rosmalen. Q. Pellel, J. A. Schouten, and J. P. J. Michels,SPE Prod. Eng. (Aug. 1991 ), p. 343.
E. M. Dantzler, C. M. Knobler, and M. L. Windsor,J. Phys. Chem. Ithaca 72;676 (1968).
R. D. Gunn, M.S. thesis (University of California, Berkeley, 1958).
A. E. Hoover, I. Nagata, T. W. Leland, Jr., and R. Kobayshi,J. Chem. Phys. 48;2633 (1968).
D. McA. Mason and B. E. Eakin,J. Chem. Eng. Data 6:499 (1961).
C. J. Wormald, E. J. Lewis, and D. J. Hutchings,J. Chem. Thermodyn. 11;1 (1979).
W. M. Haynes, R. D. McCarty, B. E. Eaton, and J. C. Holste,J. Chem. Thermodyn. 17;309 (1985).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Blanke, W., Weiss, R. Virial coefficients of methane-ethane mixtures in the temperature range from 0 to 60°C determined with an automated expansion apparatus. Int J Thermophys 16, 643–653 (1995). https://doi.org/10.1007/BF01438849
Issue Date:
DOI: https://doi.org/10.1007/BF01438849