Abstract
Oxidation of 1,2,4,5-tetrafluoro-3,6-bus (vinylthio)benzene (1) affords 1,2,4,5-tetra fluoro3,6-bis(vinylsulfonyl)benzene (2) in 65 % yield. The reaction of compound 2 with allylamine gives a new heterocyclic compound, 5,6-difluorobenzo-[a,d]-bis(3,3′-dihydro-l,l′-sulfonylallyl-4,4′-perhydroazine) (3). This compound is the product of nucleophilic addition at the vinylsulfonyl group and intramolecular replacement of fluorine atoms of the benzene ring. The structure of compound 3 has been established by X-ray structural study.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 430–433, February, 1996.
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Amosova, S.Y., Gostevskaya, V.I., Gavrilova, G.M. et al. New heterocyclic system based on vinylsulfonylfluorobenzene and X-ray structural study of this compound. Russ Chem Bull 45, 414–416 (1996). https://doi.org/10.1007/BF01433984
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DOI: https://doi.org/10.1007/BF01433984