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Fragmentation of 1-hydroxy-2-(5H-dibenzo[a,d]cyclohepten-5-yl)-1-phenylethyl cation in superacid

  • Organic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The 1-hydroxy-2-(5H-dibenzo[a,d]cyclohepten-5-yl)-1-phenylethyl cation generated under “long life” conditions undergoes fragmentation to afford 5H-dibenzo[a,d]cycloheptenyl-and methylphenylhydroxycarbinyl canons but does not undergo carbocationic cyclization.

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Authors and Affiliations

  1. Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 7 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russia

    S. A. Osadchii, V. I. Mamatyuk & V. G. Shuhin

  2. Department of Organic Chemistry, Bucharest Polytechnic Institute, 76206, Bucharest, Romania

    M. D. Stanescu

Authors
  1. S. A. Osadchii
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  2. M. D. Stanescu
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  3. V. I. Mamatyuk
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  4. V. G. Shuhin
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 397–399, February, 1996.

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Osadchii, S.A., Stanescu, M.D., Mamatyuk, V.I. et al. Fragmentation of 1-hydroxy-2-(5H-dibenzo[a,d]cyclohepten-5-yl)-1-phenylethyl cation in superacid. Russ Chem Bull 45, 381–383 (1996). https://doi.org/10.1007/BF01433977

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  • DOI: https://doi.org/10.1007/BF01433977

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