Abstract
Alkaline nitrobenzene oxidation of hardwood and softwood lignins in the presence of redox and phase-transfer catalysts was studied. The selectivity of oxidation of lignins increased by 1.7 to 1.9 times. A possible mechanism of catalysis is discussed.
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References
Lignins, Eds. K. V. Sarkanen and C. H. Ludwig, Wiley, New York-London-Sydney-Toronto, 1971.
M. I. Chudakov,Promyshlennoe ispol'zovanie lignina [Industrial Use of Lignin], Lesn. promyshlennost', Moscow, 1983, 200 pp. (in Russian).
V. E. Taraban'ko, N. V. Koropachinskaya, A. V. Kudryashov, and B. N. Kuznetsov,Izv. Akad. Nauk, Ser. Khim., 1995, 375 [Russ. Chem. Bull., 1995,44, 367 (Engl. Transl.)].
B. D. Bogomolov and V. S. Butsalenko, inChromatograficheskii analiz v khimii drevesiny [Chromatographic Analysis in Wood Chemistry], Zinatne, Riga, 1975, 87 (in Russian).
O. D. Kamaldina and Ya. A. Massov,Poluchenie vanilina iz fignosulfatov [Manufacture of Vanillin from Lignosulfates], CBTI CINIS, Moscow, 1959 (in Russian).
K. K. Lebedev,Trudy isentral'nogo nauchno-issled, lesokhim, instituta [Proceedings of the Central Research Institute of Wood Chemistry], Gorky, 1965, Issue 16, 53 (in Russian),
O. P. Grushnikov and V. V. Elkin,Dostizheniya i problemy khimii lignina [Advances and Problems of Lignin Chemistry], Nauka, Moscow, 1973, 42 pp. (in Russian).
N. M. Emanuel, inXII Mendeleevskii s'ezd po obshchei i prikladnoi khimii; Plenum. Dokl. [XII Mendeleev Congress on General and Applied Chemistry, Plenary Lecture], Nauka, Moscow, 1984, 141 (in Russian),
B. Kh. Pulatov and Kh. A. Abduazimov, inProblemy kompleksnogo ispol'zovaniya drevesnogo syr'ya, Tez, Dokl. [Problems of Extensive Use of Wood Pulp], Riga, 1985, 87.
E. I. Germer and Yu. G. Butko,Khimiya Drevesiny [Wood Chemistry], 1983, No. 5, 32 (in Russian).
Russian Pat. 2040617, 1993,Byull, Izobret., 1995, No. 21, 184,
A. F. Gogotov, T. I. Makovskaya, and V. A. Babkin,Zh. Prikl. Khim., 1996,69, 870 [J, Appl. Chem. Russ. 1996,69 (Engl. Trans.)].
Application 92006389 Russian Federation,Byull. Izobret., 1995, No. 33, 34.
V. M. Nikitin,Teoreticheskie asnovy delignifikatsii [Theoretical Bases of Delignification], Lesnaya Promyshlennost, Moscow, 1981, 244 pp. (in Russian).
S. M. Shevchenko and I. P. Deineko,Khimiya Drevesiny [Wood Chemistry], 1983, No.6, 3 (in Russian).
V. M. Reznikov and I. V. Sen'ko, inKhimiya drevesiny [Wood Chemistry], Zinatne, Riga, 1968, 51 (in Russian).
M. A. Zil'bergleit, Ya. G. Mileshkevich, T. V. Korneichik, inSed'maya Vsesoyuznaya Konferentsiya po Khimii ilspol'zovaniyu Lignina, Ted. Dokl., [Abstr, of Seventh All-Union Conference on Applied Chemistry of Lignin], Zinatne, Riga, 1987, 53 (in Russian).
I. M. Luzhanskaya, A. D. Sergeev, E. I. Chupka, inSed'maya Vsesoyuznaya Konferentsiya pa Khimii i lspol'zovaniyu Lignina, Tez. Dokl., [Abstr. of Seventh AllUnion Conference on Applied Chemistry of Lignin), Zinatne, Riga, 1987, 102 (in Russian),
A. D. Venica, Chen-Loung Chen, and J. S. Gratzl, in4-th Int. Symp. Wood and Pulp Chem., Raleigh, 1989, 261
T. M. Saleh and H. F. Mohammed,Indian Pulp and Pap. J. 1986,30, No 6, 1
L. V. Kanitskaya, I. D. Kalikhman, S. A. Medvedeva, I. A. Behusova, V. A. Babkin, and G. A, Kalabin,Khimiya Drevesiny [Wood Chemistry], 1992, No. 4–5, 73 (in Russian).
S. S. Yufit,Zh. Vsesoyuz. Khim. obshch, im. D. l. Mendeleeva, 1986,31, 134 [Mendeleev Chem. J., 1986,31 (Engl. Transl.)].
A. F. Gogotov, A. N. Zakazov, and V. A. Babkin, inMezhfaznyi Kataliz. Novye Idei i Metody. Tez. Dokl. [Phase-Transfer Catalysis: Trends and Methods. Abstracts of Conference], Moscow, 1994, 26 (in Russian).
Application 92010800 Russian Federation,Byull. Izobret., 1995, No. 33, 34 (in Russian),
J. M. Pepper and J. C. Karapally,Pulp. and Pap. Mag. Can., 1972,73, No. 9, 88.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 3004–3007, December, 1996.
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Gogotov, A.F., Rybal'chenko, N.A., Makovskaya, T.I. et al. Catalytic nitrobenzene oxidation of lignins. Russ Chem Bull 45, 2854–2857 (1996). https://doi.org/10.1007/BF01430660
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DOI: https://doi.org/10.1007/BF01430660