Skip to main content
Log in

Formation of poly-p-phenylene thin films and their composites with fullerene by discrete evaporation in vacuum

  • Physical Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The effect of parameters of discrete evaporation of poly-p-phenylene (PPP) and C60 on quality of the films formed was studied, PPP and PPP/C60 composite films and heterostructures based on these materials were prepared. It was established that the conjugation length of PPP macromolecules consists of −9–10 units, and they can be electrochemically transformed into the radical cation state at a potential of 2.10 V. Glassy carbon-PPP-C60-Al heterostructures with a rectification ratio of 106–108 were formed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. G. Grem, V. Martin, F. Meghdadi, C. Paar, J. Stampfl, J. Sturm, S. Tasch, and G. Leizing,Synt. Met., 1995,71, 2193.

    Article  Google Scholar 

  2. G. Pakbaz and A. Heeger,Appl. Phys. Lett., 1994,64, 3422.

    Google Scholar 

  3. Y. Kogan, V. V. Abalyaeva, A. A. Zachidov, and S. B. Lee,Synt. Met., 1991,42, 1439.

    Google Scholar 

  4. P. Covacic and J. Oziomek,J. Org. Chem., 1964,29, 100.

    Google Scholar 

  5. H. Werner, Th. Schedel-Nietrig, M. Wohlers, D. Herein, B. Herzog, R. Schlogl, M. Reil, A. M. Bradshaw, and J. Kirschner,J. Chem. Soc., Faraday Trans., 1994,90, 403.

    Google Scholar 

  6. L. W. Shacklette, H. Eckhardt, R. R. Chance, G. G. Miller, D. M. Ivory, and R. H. Baughman,J. Chem. Phys., 1979,73, 4098.

    Google Scholar 

  7. G. Leising, K. Pichler, and F. Stelzer,Springer Series in Solid State Sciences, 1989,91, 100.

    Google Scholar 

  8. S. B. Lee, P, K. Khabibulaev, A, A. Zachidov, S. Morita, and K. Yoshino, inIntern. Conf. on Science and Technology of Synthetic Metals, Abstracts, Seoul, Korea, 1994, 645.

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No, 12, pp, 2918–2921, December, 1996.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kogan, I.L., Belov, M.Y., Fokeeva, L.S. et al. Formation of poly-p-phenylene thin films and their composites with fullerene by discrete evaporation in vacuum. Russ Chem Bull 45, 2769–2772 (1996). https://doi.org/10.1007/BF01430640

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01430640

Key words

Navigation