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Hyperfine structure in low-lying levels of PtII, AuII and BiII

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Zeitschrift für Physik D Atoms, Molecules and Clusters

Abstract

Far UV lines in the spectra of PtII, AuII and BiII emitted by a hollow-cathode lamp exhibit Fabry-Perot patterns, which are used for determining the hyperfine structure of the low-lying levels of these three spectra and the isotopic shifts in five lines of PtII. The experimental data are compared with those computed through the relativistic Dirac-Fock method. The effect of spin polarisation is discussed. In the case ofd electrons the Hartree-Fock method with spin polarisation is used for explaining the large ratio between the spin polarisation and relativistic effects.

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Authors and Affiliations

  1. Laboratoire de Spectrométrie et Optique Laser, Faculté des Sciences et Techniques, 6 av. Le Gorgeu, F-29287, Brest Cedex, France

    S. Bouazza

  2. Laboratoire Aimé Cotton, C.N.R.S. II, Campus d'Orsay, F-91405, Orsay Cedex, France

    J. Bauche

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  1. S. Bouazza
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  2. J. Bauche
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Bouazza, S., Bauche, J. Hyperfine structure in low-lying levels of PtII, AuII and BiII. Z Phys D - Atoms, Molecules and Clusters 10, 1–11 (1988). https://doi.org/10.1007/BF01425576

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  • DOI: https://doi.org/10.1007/BF01425576

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