Summary
Coordination compounds formed by the interaction of 2- and 4-benzylpyridines with some bivalent metal halides and pseudohalides have been prepared and characterized by molecular conductance, magnetic susceptibility, electronic and i.r. spectral measurements down to 200 cm-1 in the solid state. Tentative stereochemistries for the complexes isolated in the solid state are suggested. The ligand-field parameters 10 Dq, B, β, λ and v2 /v, are calculated for the cobalt(II) and nickel(II) complexes and are consistent with their proposed stereochemistries.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
D. P. Graddon, K. B. Heng and E. C. Watton,Austr. J. Chem., 21, 121 (1968).
C. H. Cline and J. Turkevich,J. Chem. Phys., 12, 300 (1953); J. K. Wilmshurst and H. J. Bernstein,Can. J. Chem., 35, 1171 (1957); D. A. Long, F. S. Murfin and E. L. Thomas,Trans. haradav Soc., 59, 12 (1963).
N. S. Gill, R. H. Nutall, D. E. Scaife and D. W. A. Sharp,J. Inorg. Nucl. Chem. 18, 79 (1961).
H. Fischer, W. J. Galloway and J. Vaughan,J. Chem. Soc., 3591 (1964).
R. J. H. Clark in V. Gutmann Ed.,Halogen Chemistry, Vol. 3, Academic Press, New York, 1968.
D. M. Adams,Metal-Ligand and Related Vibrations, Edward Arnold, London, 1967.
C. K. Jorgensen,Absorption Spectra and Chemical Bonding in Complexes, Pergamon Press, London 1962.
J. D. Dunitz,Acta Crystallogr. 10, 307 (1957); (8b) M. Goldstein, E. F. Mooney, A. Anderson and H. A. Gebbie,Spectrochini. Acta, 21, 105 (1965).
C. Furlani,Coord. Chem. Revs., 3, 141 (1968).
J. N. Brown, H. R. Eichelberger, E. Schaffer, M. L. Good and L. M. Trefonas,J. Am. Chent. Soc., 93, 629 (1971).
D. M. Adams, J. Chatt, J. M. Davidson and J. Gerratt,J. Chem. Soc., 2189 (1963); G. B. Deacon, J. H. S. Green and D. J. Harrison,Spectrochim. Acta, 24A, 1921 (1968).
I. S. Ahuja and Rajindar Singh,J. Inorg. Nucl. Chem., 35, 3 (1973); I. S. Ahuja and Raghuvir Singh,ibid, 36, 1505 (1974).
D. Grdenic and I. Krstanovic,Arkiv. Kemi, 27, 143 (1955).
I. S. Ahuja and P. Rastogij.Chem. Soc. A, 378, 2161 (1970).
R. A. Bailev, S. L. Kozak, I. W. Michelsen and W. N. Mills,Coord. Chem. Revs., 6, 407 (1970).
I. S. Ahuja and Raghuvir Singh,J. Coord. Chem., 4, 181 (1975).
A. D. Liehr and C. J. Ballhausen,Ann. Phys., New York, 6, 134 (1959).
I. S. Ahuja and A. Garg,J. Inorg. Nucl. Chem., 34, 1929 (1972).
J. Hvoslef,Acta Chem. Scand, m12, 1568 (1958).
L. H. Jones,J. Chem. Phys., 27, 665 (1957).
I. S. Ahuja and RaghuvirSingh Singh,Inorg. Cbirn. Acta, 7, 565 (1973);Inorg. Nucl. Chem. Lett., 10, 421 (1974); I. S. Ahuja and K.K. Sambasivarao,J. Inorg. Nucl. Chem., 36, 586 (1975).
A. R. Davis, C. J. Murphy and R. A. Plane,Inorg. Chem., 9, 423 (1970); I. S. Ahuja and A. Garg,J. Inorg. Nucl. Chem., 34, 2074 (1972).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ahuja, I.S., Singh, R. & Sriramulu, R. 2- and 4-benzylpyridine complexes with bivalent metal halides and pseudohalides. Transition Met Chem 3, 185–190 (1978). https://doi.org/10.1007/BF01393542
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01393542