Summary
The monodentate ligands, L, ethylamine, butylamine, cyclohexylamine, benzylamine, piperidine and morpholine, and bidentate ligands, L, 1,10-phenanthroline and 2,2′-bipyridyl react with tetracarbonylbis(η-cyclopentadienyl)diiron to give monosubstituted derivatives, (η-C5H5)2Fe2(CO)3L, and with iododicarbonyl(η-cyclopentadienyl)iron to yield ionic products, [(η-C5H5)Fe(CO)2L]I. I.r. spectral studies suggest that two isomeric (η-C5H5)2-Fe2(CO)3L molecules exist.
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Tripathi, S.C., Srivastava, S.C. & Pandey, V.N. Tricarbonylbis(η-cyclopentadienyl)diiron and iododicarbonyl(η-cyclopentadienyl)iron amine complexes. Transition Met Chem 1, 58–60 (1976). https://doi.org/10.1007/BF01385942
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DOI: https://doi.org/10.1007/BF01385942