Abstract
A survey of hyperfine analyses in the low-lying configurations 4f n6s 2, 4f n5d6s, 4f n6s6p, and 4f n−1 5d6s 2 of the lanthanides is given. Experimental hf radial integrals 〈r −3〉 kj nl are indicated for the configurations under investigation. From a comparison of experimental and theoretical hf radial integrals configuration-interaction contributions Δ kj nl to the hfs have been evaluated for the configurations for which corresponding integrals were available. With nuclear electric quadrupole moments from muonic x-ray investigations and radial integrals 〈r −3〉 01 nl and 〈r −3〉 02 nl from experimental hfs quadrupole shielding correctionsR 01 nl have been obtained. The variation of hyperfine radial integrals, configuration-interaction contributions and quadrupole shielding corrections over the 4f shell in the configurations under study is discussed. Trends of these quantities in different configurations are compared.
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Pfeufer, V. On the hyperfine structure in the configurations 4f n6s 2, 4f n5d6s, 4f n6s6p, and 4f n−15d6s 2 of the lanthanides. Z Phys D - Atoms, Molecules and Clusters 4, 351–366 (1987). https://doi.org/10.1007/BF01384888
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DOI: https://doi.org/10.1007/BF01384888