Abstract
A systematic analysis of the experimental data on intermolecular interactions in solutions has shown that London -Debye-Keesom potentials can be used to evaluate the influence of the universal intermolecular interactions on the enthalpy of the nonspecific soIvation of organic nonelectrolytes.
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B. N. Solomonv, V. B. Novikov, and A. Z. Konovalov, “Evaluation of the energies of intermolecular interactions with the use of data on the heat of solution,” Dokl. Akad. Nauk SSSR,255, No. 5, 1181–1184 (1980).
B. N. Solomonov and A. Z. KonovaIov, “New approach to the analysis of the heat of solvaion of organic nonelectrolytes,” Zh. Obshch. Khim.,5, No, 11, 2529–2546 (1985).
O. E. Kiselev, G. A. Martynov, B. N. Solomonov, and A. N. Konovalov, “Calculation of the heat of solvation on the basis of equations from the theory of liquids,” Dokl. Akad. Nauk SSSR,292, No. 3, 624–628 (1987).
V. V. Prezhdo, “Criteria for the formation of complexes by molecules in solutions,” Teor. Éksp. Khim.,22, No. 6, 729–733 (1986).
B. N. Solomonov, A. I. Konovalov, V. B. Novikov, et al., “Solvation of organic compounds. Determination of the enthalpy of the specific interaction between a solute and a solvent,” Zh. Obshch. Khim.,55, No. 9, 1889–1906 (1985).
B. N. Solomouov, I. S. Antipin, V. B. Novikov, and A. I. Konovalov, “Solvation of organic compounds in cyclohexane. New method for evaluating the heats of vaporization of substances,” ibid.,52, No. 12, 2681–2688 (1982),
W. K. Stephenson and R. Fuchs, “Enthalpies of interaction of nitrogen base solutes with organic solvents,” Can,. J. Chem.,63, 2540–2543 (1985).
W. K. Stephenson and R. Fuchs, “Enthalpies of interaction of ketones with organic solvents,”163, 336–340 (1985).
W. K. Stephenson and R. Fuchs, “Enthalpies of interaction of hydroxylic solutes with organic solvents,” ibid.,63, 2535–2539 (1985).
W. K. Stephenson and R. Fuchs, “Enthalpies of interaction of aromatic solutes with organic solvents,” ibid.,63, 2529–2534 (1985).
B. N. Solomonov, A. I. Konovalov, V. B. Novikov, et al., “Solvation of organic compounds. Molecular refraction, dipole moment, and heat of solvation,” Zh. Obshch. Khim.,54, No. 7, 1622–1631 (1984).
Additional information
Kharkov Polytechnical Institute. Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 27, No. 1, pp. 70–75, January–February, 1991. Original article submitted February 13, 1989.
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Prezhdo, V.V., Bocharova, V.V. & Prezhdo, O.V. Influence of intermolecular interactions on the heat of solvation of nonelectrolytes. Theor Exp Chem 27, 66–71 (1991). https://doi.org/10.1007/BF01372927
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DOI: https://doi.org/10.1007/BF01372927