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Reactivity of hexafluoride complexes of group IV-a elements

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Abstract

By means of the SCF MO LCAO method in the MNDO approximation, electronic and spatial structures have been calculated for complexes EF 2−6 (E = Si, Ge, Sn) and also certain aqua derivatives of these complexes. It has been shown that an associative substitution mechanism may be realized for SnF 2−6 , a conclusion that is supported by data on the kinetics of hydrolysis.

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Authors
  1. V. N. Plakhotnik
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  2. L. A. Yaryshkina
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  3. V. V. Rossikhin
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Additional information

Dnepropetrovsk Institute of Rail Transport Engineers. Translated from Teoreticheskaya i Éksperimental'naya khimiya, Vol. 27, No. 4, pp. 491–493, July–August, 1991. Original article submitted October 12, 1990.

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Plakhotnik, V.N., Yaryshkina, L.A. & Rossikhin, V.V. Reactivity of hexafluoride complexes of group IV-a elements. Theor Exp Chem 27, 429–431 (1991). https://doi.org/10.1007/BF01372524

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  • DOI: https://doi.org/10.1007/BF01372524

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