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Synthesis, Crysta Structure, and Some Propertie of 4-Hydroxymethylpyridinium Hexafluorosilicate

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Abstract

Hexafluorosilicate with the composition (LH)2SiF6 (I), (L = 4-hydroxymethylpyridine) is isolated as the interaction product of an L methanol solution and 45% hydrofluorosilicic acid (L:H2SiF6 = 1:3). It the crystal structure of I the cations and anions are linked by NH···F (N···F of 2.809(2) Å,2.824(2) Å) and OH···F (O···F of 2.7036(18) Å) H bonds; the geometry of the SiF62− anion is a distorted octahedron (Si–F distances 1.6780(11)-1.6877(11) Å). In the IR spectrum of I the absorption bands of the main vibrations are identified; the solubility of I in water and some organic solvents and the degree of hydrolysis of the salt in a 1·10−4 M aqueous solution are determined.

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References

  1. T. Suge, A. Kawasaki, K. Ishikawa, T. Matsuo, and S. Ebisu. Dent. Mater., 2008, 24, 192–198.

    Article  CAS  PubMed  Google Scholar 

  2. N. A. Brsikyan, L. H. Andriasyan, G. R. Badalyan, A. V. Harutyunyan, A. M. Petrosyan, and V. V. Ghazaryan. The New Armenian Med. J., 2012, 6, 52–55.

    Google Scholar 

  3. Y. Hosoya, K. Tadokore, H. Otani, K. Hidaka, T. Inoue, M. Miyazaki, and F. R. Tay. J. Oral Science, 2013, 55, 115–121.

    Article  CAS  Google Scholar 

  4. V. O. Gelmboldt, Ed. V. Ganin, M. M. Botoshansky, V. Yu. Anisimov, O. V. Prodan, V. Ch. Kravtsov, and M. S. Fonari. J. Fluorine Chem., 2014, 160, 57–63.

    Article  CAS  Google Scholar 

  5. V. O. Gelmboldt, V. Yu. Anisimov, I. O. Shyshkin, M. S. Fonari, and V. Ch. Kravtsov. J. Fluorine Chem., 2018, 205, 15–21.

    Article  CAS  Google Scholar 

  6. V. O. Gelmboldt, V. Yu. Anisimov, I. O. Shyshkin, M. S. Fonari, and V. Ch. Kravtsov. Pharm. Chem. J., 2018, 52, 606–610.

    Article  CAS  Google Scholar 

  7. T. Suge, A. Kawasaki, K. Ishikawa, T. Matsuo, and S. Ebisu. Dent. Mater., 2010, 26, 29–34.

    Article  CAS  PubMed  Google Scholar 

  8. A. A. Altaf, A. Shahzad, Z. Gul, N. Rasool, A. Badshah, B. Lal, and E. Khan. J. Drug Des. Med. Chem., 2015, 1, 1–11.

    Google Scholar 

  9. A. Borowiak-Resterna, J. Szymanowski, and A. Voelkel. J. Radioanalyt. Nucl. Chem., 1996, 208, 75–86.

    Article  CAS  Google Scholar 

  10. European Pharmacopoeia, 7th ed. Strasbourg: Council of Europe, 2010.

  11. W. F. Finney, E. Wilson, A. Callender, M. D. Morris, and L. W. Beck. Environ. Sci. Technol., 2006, 40, 2572–2577.

    Article  CAS  PubMed  Google Scholar 

  12. G. M. Sheldrick. Acta Crystallogr., 2008, A64, 112–122.

    Article  CAS  Google Scholar 

  13. R. Uhrecky, J. Pavlik, Z. Ruzickova, L. Dlhan, M. Koman, R. Boca, and J. Moncol. J. Mol. Struct., 2014, 1076, 10–19.

    Article  CAS  Google Scholar 

  14. S. Suckert, L. S. Germann, R. E. Dinnebier, J. Werner, and C. Nather. Crystals., 2016, 6, 38.

    Article  CAS  Google Scholar 

  15. K. Nakamoto. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th ed. Wiley: New York, 1986.

    Google Scholar 

  16. A. Ouasri, F. Lambarki, A. Rhandour, Ts. K. Zahariev, N. Trendafilova, and I. Georgieva. Vibrat. Spectr., 2017, 88, 83–93.

    Article  CAS  Google Scholar 

  17. Abolghasem Jouyban. Handbook of Solubility Data for Pharmaceuticals. Boca Raton: CR. Press, Taylor & Frances Group, 2010.

    Google Scholar 

  18. V. O. Gelmboldt, Ed. V. Ganin, M. S. Fonari, L. V. Koroeva, Yu. E. Ivanov, and M. M. Botoshansky. J. Fluorine Chem., 2009, 130, 428–433.

    Article  CAS  Google Scholar 

  19. V. O. Gelmboldt. Russ. J. Inorg. Chem., 2014, 59, 79–83.

    Article  CAS  Google Scholar 

  20. G. A. Geffrey. An Introduction to Hydrogen Bonding. Oxford University Press: Oxford, 1997.

    Google Scholar 

  21. A. Pevec and A. Demšar. J. Fluorine Chem., 2008, 129, 707–712.

    Article  CAS  Google Scholar 

  22. E. A. Goreshnik, V. O. Gelmboldt, L. V. Koroeva, and Ed. V. Ganin. J. Fluorine Chem., 2011, 132, 138–142.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Odessa National Medical University, Odessa, Ukraine

    V. O. Gelmboldt & I. O. Shyshkin

  2. Institute of Applied Physic, Chisinau, Republic of Moldova

    M. S. Fonari & V. Kh. Kravtsov

Authors
  1. V. O. Gelmboldt
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  2. I. O. Shyshkin
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  3. M. S. Fonari
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  4. V. Kh. Kravtsov
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Corresponding authors

Correspondence to V. O. Gelmboldt or M. S. Fonari.

Additional information

Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 7, pp. 1197-1202.

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Gelmboldt, V.O., Shyshkin, I.O., Fonari, M.S. et al. Synthesis, Crysta Structure, and Some Propertie of 4-Hydroxymethylpyridinium Hexafluorosilicate. J Struct Chem 60, 1150–1155 (2019). https://doi.org/10.1134/S0022476619070175

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  • DOI: https://doi.org/10.1134/S0022476619070175

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