Skip to main content
Log in

Ability of coordination-unsaturated metallocomplexes to bind and transport chloride anions through bilayer lipid membranes

  • Published:
Theoretical and Experimental Chemistry Aims and scope

Abstract

The ability of coordination-unsaturated lipophilic metallocomplexes to bind and transport chloride anions through bilayer lipid membranes, which are usually used as a model of biological membranes, has been theoretically substantiated and experimentally confirmed. It is suggested that a similar transport mechanism can occur in processes of passive and active transport in biological membranes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. E. E. Kriss, A. S. Volchenskova, A. S. Grigor'eva et al., Coordination Compounds of Metals in Medicine [in Russian], Naukova Dumka, Kiev (1986).

    Google Scholar 

  2. A. M. Omel'chenko, B. A. Bovykin, T. V. Sytnik, et al., Dokl. Akad. Nauk SSSR,301, No.5, 1238–1241 (1988).

    PubMed  Google Scholar 

  3. A. M. Omel'chenko, B. A. Bovykin, and P. A. Grigor'ev, ibid.,309, No.1, 236–239 (1989).

    Google Scholar 

  4. J. Bjerrum, The Formation of Metal Ammines in Aqueous Solution [Russian translation], Izd. Inostr. Lit., Moscow (1961).

    Google Scholar 

  5. A. I. Stetsenko and L. B. Sel'derkhanova, Dokl. Akad. Nauk SSSR,259, No.6, 1378–1381 (1981).

    Google Scholar 

  6. E. Amis, Influence of the Solvent on the Rate and Mechanism of Chemical Reactions [Russian translation], Mir, Moscow (1968).

    Google Scholar 

  7. O. A. Osipov, V. I. Minkin, and A. D. Garnovskii, Handbook of Dipole Moments [in Russian], Vysshaya Shkola, Moscow (1971).

    Google Scholar 

  8. V. P. Topaly, É. E. Topaly, and V. I. Bregadze, Biol. Membr.1, No.2, 200–210 (1984).

    Google Scholar 

  9. A. V. Babakov, I. V. Myagkov, P. S. Sotnikov, and O. P. Terekhov, Biofizika,17, No.2, 347–350 (1972).

    PubMed  Google Scholar 

  10. C. Hansch and A. Leo, Substituent Constants for Correlation Analysis in Chemistry and Biology, Wiley, New York (1979). !

    Google Scholar 

  11. P. Mueller, D. O. Rudin, H. T. Tien, and W. C. Weseott, J. Phys. Chem.,67, No.2, 534–535 (1963).

    Google Scholar 

Download references

Authors

Additional information

Dnepropetrovsk Chemicotechnological Institute. Translated from Teoreticheskaya i Ékspe-rimentaI'naya Khimiya, Vol. 27, No. 3, pp. 382–387, May–June, 1991. Original article submitted February 15, 199l.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bovykin, B.A., Omel'chenko, A.M. & Sytnik, T.V. Ability of coordination-unsaturated metallocomplexes to bind and transport chloride anions through bilayer lipid membranes. Theor Exp Chem 27, 332–336 (1991). https://doi.org/10.1007/BF01372504

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01372504

Keywords

Navigation