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Crystal and molecular structure of binuclear copper acetate mono-α-picoline

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Abstract

Green, needle-shaped crystals of copper acetate mono-α-picoline, Cu(ac)2-(α-pic), crystallize in space groupP21/c with cell dimensionsa=7.675(4),b=20.008(6),c=8.207(4)Å, and β=115.99(3) °. The crystal structure has been solved by the heavy-atom method and refined with the three-dimensional x-ray photographic data to anR factor of 9.2%. The structure consists of binuclear units Cu2(ac)4(α-pic)2. The Cu-Cu distance is 2.671 Å. The bond length Cu-N (2.24 Å) is significantly longer than the corresponding distance in analogous complexes.

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Authors and Affiliations

  1. Department of Analytical Chemistry, Pharmaceutic Faculty of the Komensky University, Qdbojárov 10, 88034, Bratislava, Czechoslovakia

    F. Pavelčík

  2. Institute of Inorganic Chemistry, Slovak Academy of Sciences, Dúbravská cesta, 80934, Bratislava, Czechoslovakia

    F. Hanic

Authors
  1. F. Pavelčík
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  2. F. Hanic
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Pavelčík, F., Hanic, F. Crystal and molecular structure of binuclear copper acetate mono-α-picoline. Journal of Crystal and Molecular Structure 8, 59–65 (1978). https://doi.org/10.1007/BF01371517

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  • DOI: https://doi.org/10.1007/BF01371517

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