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Electromotive behaviour of anion selective membranes with triorganotin acetates as ionophores and nucleophiles as additives

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Abstract

The electromotive behaviour of neutral carrier based Cl−-selective electrodes can be improved if lipophilic nucleophiles are added to the membrane phase containing triorganotin acetates as anion carriers. The addition of about 50 mol-% octadecanethiol to diethyl-n-hexyltin acetate as ionophore leads to improved sensor response times and to slopes of the electrode response function close to the Nernstian behaviour.

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References

  1. J. D. Czaban,Anal. Chem. 1985,57, 345A.

    Google Scholar 

  2. G. N. Bowers Jr., C. Brassard, S. F. Sena,Clin. Chem. 1986,32, 1437.

    Google Scholar 

  3. U. Oesch, D. Ammann, W. Simon,Clin. Chem. 1986,32, 1448.

    Google Scholar 

  4. D. Wegmann, H. Weiss, D. Ammann, W. E. Morf, E. Pretsch, K. Sugahara, W. Simon,Mikrochim. Acta [Wien] 1984,III, 1.

    Google Scholar 

  5. H. B. Herman, G. A. Rechnitz,Anal. Chim. Acta 1975,76, 155.

    Google Scholar 

  6. W. J. Scott, E. Chapoteau, A. Kumar,Clin. Chem. 1986,32, 137.

    Google Scholar 

  7. M. E. Meyerhoff, E. Pretsch, D. H. Welti, W. Simon,Anal. Chem. 1987,59, 144.

    Google Scholar 

  8. U. Wuthier, H. V. Pham, B. Rusterholz, W. Simon,Helv. Chim. Acta 1986,69, 1435.

    Google Scholar 

  9. H. V. Pham, D. Welti, E. Pretsch, W. Simon, in preparation.

  10. U. Oesch, D. Ammann, H. V. Pham, U. Wuthier, R. Zünd, W. Simon,J. Chem. Soc., Faraday Trans. 1,1986,82, 1179.

    Google Scholar 

  11. U. Oesch, P. Anker, D. Ammann, W. Simon,Ion-Selective Electrodes, Akadémiai Kiadó, Budapest, 1985, p. 81.

    Google Scholar 

  12. M. Gielen, I. V. Eynde,J. Soc. Chim. Belg. 1981,90, 195.

    Google Scholar 

  13. R. E. Dohner, D. Wegmann, W. E. Morf, W. Simon,Anal. Chem. 1986,58, 2585.

    Google Scholar 

  14. G. G. Guilbault, R. A. Durst, M. S. Frant, H. Freiser, E. H. Hansen, T. S. Light, E. Pungor, G. Rechnitz, N. M. Rice, T. J. Rohm, W. Simon, J. D. R. Thomas,Pure Appl. Chem. 1976,48, 127.

    Google Scholar 

  15. P. Henderson,Z. Phys. Chem. 1907,59, 118.

    Google Scholar 

  16. P. Henderson,Z. Phys. Chem. 1908,63, 325.

    Google Scholar 

  17. P. C. Meier,Anal. Chim. Acta 1981,136, 363.

    Google Scholar 

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Authors and Affiliations

  1. Department of Organic Chemistry, Swiss Federal Institute of Technology (ETH), Universitätsstrasse 16, CH-8092, Zürich, Switzerland

    Urs Wuthier & Wilhelm Simon

Authors
  1. Urs Wuthier
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  2. Wilhelm Simon
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Wuthier, U., Simon, W. Electromotive behaviour of anion selective membranes with triorganotin acetates as ionophores and nucleophiles as additives. Mikrochim Acta 90, 225–234 (1986). https://doi.org/10.1007/BF01364303

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  • DOI: https://doi.org/10.1007/BF01364303

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