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On hindered rotation of NO −2 in KCl

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Zeitschrift für Physik

Abstract

Devonshire's model of a rigid dumb-bell subjected to a potential of octahedral symmetry is extended toC 2v rotors. As a practical example the low-lying energy states of NO −2 in KCl are evaluated and the allowed dipole transitions are compared with the experimental rotation-vibration spectrum at 15 °K.

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Authors and Affiliations

  1. Physikalisches Institut der Universität Freiburg i. Br., Deutschland

    P. Sauer

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  1. P. Sauer
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The author is indebted to Prof. Dr. Dr. h.c. S.Flügge for his advice and many helpful discussions during the course of this work. The numerical calculations were performed on the IBM computers 7090 Darmstadt and 7040 Freiburg i. Br. The grant of computing time is gratefully acknowledged.

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Sauer, P. On hindered rotation of NO −2 in KCl. Z. Physik 199, 280–289 (1967). https://doi.org/10.1007/BF01332389

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  • DOI: https://doi.org/10.1007/BF01332389

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