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Heat of formation of liquid copper alloys with 3d-transition metals

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Abstract

A calorimetric method is used to study the enthalpy of mixing in liquid copper alloys with 3d-metals. Results are compared with published information. The change in thermodynamic properties along the 3d-row is not uniform. The regularities obtained are associated with the type of phase diagrams. It is demonstrated that the change in thermodynamic characteristics is determined by features of the electron structure of the components.

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Authors
  1. M. A. Turchanin
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  2. S. V. Porokhnya
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Additional information

Donbass State Engineering Academy, Kramatorsk. Translated from Poroshkovaya Metallurgiya, Nos. 7–8, pp. 64–75, July–August, 1996.

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Turchanin, M.A., Porokhnya, S.V. Heat of formation of liquid copper alloys with 3d-transition metals. Powder Metall Met Ceram 35, 378–388 (1996). https://doi.org/10.1007/BF01329228

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