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Calorimetric Investigation of the Mixing Enthalpy of Liquid Hf-Ni-Ti Alloys and Thermodynamic Properties and Chemical Ordering in Quaternary Liquid Cu-Hf-Ni-Ti Alloys

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Abstract

The mixing enthalpies of liquid Hf-Ni-Ti alloys were measured at 1873 K by applying a high-temperature isoperibolic calorimeter. The investigation was performed along the xHf/xNi = 3 section at xTi = 0-0.64 and along the xNi/xTi = 3 section at xHf = 0-0.57. The limiting partial enthalpy of mixing of undercooled liquid titanium in liquid Hf-Ni alloy is (− 92 ± 15) kJ mol−1. The partial enthalpy of mixing of undercooled liquid hafnium at infinite dilution is (− 163 ± 12) kJ mol−1. The integral mixing enthalpies are negative nearly in the entire composition range. The thermodynamic properties of liquid quaternary alloys are modelled using the associate solution model. The amorphization ranges in ternary and quaternary systems are predicted by considering a total molar fraction of associates in liquid alloys.

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Acknowledgments

This work was supported by the Ministry of Education and Science of Ukraine under the Grant 0119U101646.

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  1. Donbas State Engineering Academy, Kramatorsk, 84313, Ukraine

    Mikhail Turchanin, Pavel Agraval, Liya Dreval & Anna Vodopyanova

  2. MSI, Materials Science International Services GmbH, 70565, Stuttgart, Germany

    Liya Dreval

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This invited article is part of a special tribute issue of the Journal of Phase Equilibria and Diffusion dedicated to the memory of Günter Effenberg. The special issue was organized by Andrew Watson, Coventry University, Coventry, United Kingdom; Svitlana Iljenko, MSI, Materials Science International Services GmbH, Stuttgart, Germany; and Rainer Schmid-Fetzer, Clausthal University of Technology, Clausthal-Zellerfield, Germany.

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Turchanin, M., Agraval, P., Dreval, L. et al. Calorimetric Investigation of the Mixing Enthalpy of Liquid Hf-Ni-Ti Alloys and Thermodynamic Properties and Chemical Ordering in Quaternary Liquid Cu-Hf-Ni-Ti Alloys. J. Phase Equilib. Diffus. 41, 469–490 (2020). https://doi.org/10.1007/s11669-020-00806-4

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