Abstract
The elastic constants of orthorhombic betaine calcium chloride dihydrate have been investigated by ultrasonic methods in the range between 300 and 100 K. The phase transition at 169 K is accompanied by a sharp softening of all ultrasonic waves having longitudinal components of the displacement vector, similar to the effects observed at the α-β transition of Li2Ge7O15 and at the V–IV transition of thiourea. The transition at 129 K shows only very weak anomalies like those found in the α-β transition of Te(OH)6·2NH4H2PO4·(NH4)2HPO4. The transitions at 169 K and 129 K are of second order.
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Rother, H.J., Albers, J., Klöpperpieper, A.: Ferroelectrics54, 107 (1984)
Brill, W., Schildkamp, W., Spilker, J.: Z. Kristallogr.172, 281 (1985)
Haussühl, S.: Kristallphysik. Weinheim: Physik-Verlag, Verlag Chemie, 1983
Zubov, V.G., Firsova, M.M.: Kristallografiya7, 469 (1962) (in Russian)
Haussühl, S., Wallrafen, F., Recker, K., Eckstein, J.: Z. Kristallogr.153, 329 (1980)
Haussühl, S.: Solid State Commun.46, 423 (1983)
Haussühl, S., Pähl, M.: Z. Kristallogr.176, 147 (1986)
Wada, M., Sawada, A., Ishibashi, Y.: J. Phys. Soc. Jpn.50, 1811 (1981)
Delahaigue, A., Khelifa, B., Jouve, B.: Phys. Status Solidi (B)72, 585 (1975)
Haussühl, S., Nicolau, Y.F.: Z. Phys. B — Condensed Matter61, 85 (1985)
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Haussühl, S., Liedtke, J., Albers, J. et al. Anomalous elastic properties of betaine calcium chloride dihydrate, (CH3)3NCH2COO·CaCl2·2H2O. Z. Physik B - Condensed Matter 70, 219–222 (1988). https://doi.org/10.1007/BF01318303
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DOI: https://doi.org/10.1007/BF01318303