Abstract
The title compound crystallizes in the monoclinic space groupP21/c withZ=4 and cell dimensionsa=7.724(1),b=19.274(5),c=18.638(4) Å, and β=105.68(2) °. Refinement with 1126 terms, measured with MoKα radiation on a diffractometer, has yielded a conventionalR factor of 0.059. The non-hydrogen atoms in the complex molecule were refined with anisotropic temperature factors whereas those in the acetone molecule were refined isotropically. The nitrogen atoms in the complex are not coordinated; the coordination sphere involves Co—S6 bonding of approximateD 3 symmetry, the average Co—S bond length being 2.275 Å. The geometry of the coordination sphere with respect to a definedC 3 reference axis is similar to that found in several tris(N,N′-disubstituted-dithiocarbamato)cobalt(III) complexes. The acetone molecule is hydrogen bonded to one of the amino groups, the O ⋯ N distance being 2.99 Å.
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Mackay, M.F., O'Connor, M.J. & Oliver, P.J. Crystal and molecular structure of tris(2-aminocyclopentene-1-dithiocarboxylato)-cobalt (III) monoacetone. Journal of Crystal and Molecular Structure 8, 161–174 (1978). https://doi.org/10.1007/BF01297660
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DOI: https://doi.org/10.1007/BF01297660