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Identification of the IR frequencies of the interstitial carbon atom in some M6C (M = Fe, Ru) carbonyl clusters by13 C-enrichment

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Abstract

13C-enriched carbido carbonyl clusters of the type [M6C(CO) n ]z− (M=Fe,n=16,z=2; M=Ru,n=16 ifz=2 andn=17 ifz=0) have been prepared and their IR spectra observed in the 900−600 cm−1 region; the band shifts occurring upon13 C substitution enable the assignment to the stretching modes of the interstitial C atom. Band patterns reflect the symmetry of the M6C core, but the frequencies seem dependent on other molecular features.

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References

  • Albano, V. G., and Martinengo, S. (1980)Nachr. Chem. Tech. Lab. 28, 654.

    Google Scholar 

  • Bradley, J. S., Ansell, G. B., and Hill, E. W. (1980)J. Organomet. Chem. 184, C33.

    Google Scholar 

  • Bradley, J. S. (1982) personal communication.

  • Bor, G., and Stanghellini, P. L., (1979)J. Chem. Soc. Chem. Commun., 886.

  • Bor, G., Dietler, U. K., Stanghellini, P. L., Gervasio, G., Rossetti, R., Sbrignadello, G., and Battison, G. A. (1981)J. Organomet. Chem. 213, 277.

    Google Scholar 

  • Churchill, M. K., Wormald, J., Knight, J., and Moys, M. J. (1971)J. Am. Chem. Soc. 93, 3073.

    Google Scholar 

  • Churchill, M. R., and Wormald, J. (1974)J. Chem. Soc. Dalton Trans., 2410.

  • Housecroft, C. E., Wade, K., and Smith, B. C. (1978)J. Chem. Soc. Chem. Commun., 765.

  • Oxton, I. A., Kettle, S. F. A., Jackson, P. F., Johnson, B. F. G., and Lewis, J. (1981)J. Mol. Struct. 71, 117.

    Google Scholar 

  • Sirigu, A., Bianchi, M., and Benedetti, E. (1969)J Chem. Soc. Chem. Commun., 596.

  • Tachikawa, M., and Muetterties, E. L. (1981)Progr. Inorg. Chem. 28, 203.

    Google Scholar 

  • Toth, L. E. (1971)Transition Metal Solids and Nitrides (Academic Press, New York).

    Google Scholar 

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Authors and Affiliations

  1. Department of Inorganic and General Chemistry, University of Turin, 10125, Turin, Italy

    Pier Luigi Stanghellini & Livio Cognolato

  2. Department of Industrial and Engineering Chemistry, ETH, CH-8092, Zurich, Switzerland

    György Bor

  3. School of Chemical Sciences, University of East Anglia, NR4 7TJ, Norwich, UK

    Sidney F. A. Kettle

Authors
  1. Pier Luigi Stanghellini
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  2. Livio Cognolato
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  3. György Bor
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  4. Sidney F. A. Kettle
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Stanghellini, P.L., Cognolato, L., Bor, G. et al. Identification of the IR frequencies of the interstitial carbon atom in some M6C (M = Fe, Ru) carbonyl clusters by13 C-enrichment. Journal of Crystallographic and Spectroscopic Research 13, 127–133 (1983). https://doi.org/10.1007/BF01246581

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  • DOI: https://doi.org/10.1007/BF01246581

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