Summary
The preparation, magnetic moments, i.r., reflectance and57Fe Mössbauer spectra of adducts of tris(2,2,2-trichloroethoxy)iron (III) complexes are reported. An alkoxybridged structure is supported by i.r. spectra.57Fe Mössbauer spectra are explained in terms of two inequivalent sites in highspin iron(III) octahedral symmetry.
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Abbreviations
- Pic-O:
-
α-picolineN-oxide
- Ur:
-
urea
- DMU:
-
N,N-dimethylurea
- Suc:
-
succinimide
- Diox:
-
dioxan
- Bipy:
-
2,2′-bipyridine
- Phen:
-
1,10-phenanthroline
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Chadha, S.L., Sharma, V., Taneja, S.P. et al. Tris(2,2,2-trichloroethoxy)iron(III) complexes. Transition Met Chem 11, 369–371 (1986). https://doi.org/10.1007/BF01225984
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DOI: https://doi.org/10.1007/BF01225984