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Sensitivity of determination of organosilicon and tin compounds by atomic-absorption spectroscopy

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Summary

Sensitivities for 39 organosilicon and 8 tin compounds in atomic-absorption analysis have been determined with the object of studying the relation between structure and sensitivity. A theory has been advanced in order to explain the seemingly anomalous result, that for alkylsilanes and alkyltins the sensitivity decreases as the energy of the alkyl—silicon (tin) bond decreases.

Zusammenfassung

Die Nachweis-Empfindlichkeit der Atomarabsorption für 39 organische Siliziumverbindungen und 8 organische Zinnverbindungen wurde ermittelt, um so den Zusammenhang zwischen Struktur und Empfindlichkeit zu untersuchen. Das scheinbar anormale Ergebnis, daß die Empfindlichkeit abnimmt, je geringer der Energieinhalt der Alkyl-Silizium- bzw. Alkyl-Zinn-Bindung ist, wird zu erklären versucht.

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Authors and Affiliations

  1. Department of Technical Analytical Chemistry, Lund Institute of Technology, Lund, Sweden

    I. -B. Peetre & B. E. F. Smith

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  1. I. -B. Peetre
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  2. B. E. F. Smith
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Peetre, I.B., Smith, B.E.F. Sensitivity of determination of organosilicon and tin compounds by atomic-absorption spectroscopy. Mikrochim Acta 62, 301–310 (1974). https://doi.org/10.1007/BF01219691

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  • DOI: https://doi.org/10.1007/BF01219691

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