Abstract
OH stretching fundamentals in the spectra of hydrogen-bonded crystals are accompanied by satellite bands due to sum and difference transitions involving one quantum of the OH stretching vibration and one or more quanta of the low-frequency vibration of the hydrogen bond. Such satellites were detected in the FT-IR spectra of two hydrogen-bonded crystals, ice and methanol.
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References
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NRCC No. 29006
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Falk, M. An FT-IR demonstration of the occurrence of satellite bands in the spectra of hydrogen bonds in crystals. Mikrochim Acta 94, 203–205 (1988). https://doi.org/10.1007/BF01205870
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DOI: https://doi.org/10.1007/BF01205870