Skip to main content
Log in

Structural parameters and X-ray and pycnometric densities of titanium carbonitride in its homogeneity range

  • Published:
Soviet Powder Metallurgy and Metal Ceramics Aims and scope

Conclusions

  1. 1.

    Using an isodefective sections method, a study is made of the variation of some structural parameters, in particular the lattice constant and the degree of filling of the elementary cell and its partial constituents, and density of titanium carbonitride with composition within the homogeneity range of the compound.

  2. 2.

    A method of processing available experimental data with the aid of a computer is proposed enabling a property vs composition function to be derived which is applicable with good accuracy over the whole homogeneity range of titanium carbonitride.

  3. 3.

    Overall equations are derived enabling the lattice constant and x-ray and pycnometric densities of a titanium carbonitride alloy in its homogeneity field and also the degree of filling of its elementary cell and cell constituents to be determined with good accuracy by simple calculation from the chemical composition of the alloy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. M. E. Straumanis and H. Li, Z. Anorg. Allg. Chem.,305, Nos. 3–4, 143 (1960).

    Google Scholar 

  2. S. M. Ariya, “Chemistry of variable-composition oxides,” Doctoral Dissertation, LGU, Leningrad (1963).

    Google Scholar 

  3. O. Schmidt-Dumont and K. Steinberg, Naturwissenschaften, No. 5, 117 (1954).

    Google Scholar 

  4. A. I. Avgustinik, G. M. Klimashin, and L. V. Kozlovskii, Izv. Akad. Nauk SSSR, Neorgan. Mat.,1, No. 6, 830 (1965).

    Google Scholar 

  5. V. S. Neshpor, G. M. Klimashin, and V. P. Nikitin, Refractory Carbides [in Russian], Nauk. Dumka, Kiev (1970), p. 169.

    Google Scholar 

  6. G. M. Klimashin, L. V. Kozlovskii, and R. K. Yasvina, Zh. Prikl. Khim.,44, No. 7, 1646 (1971).

    Google Scholar 

  7. G. D. Bogomolov, G. P. Shveikin, S. I. Alyamovskii, Yu. G. Zainulin, and V. D. Lyubimov, Izv. Akad. Nauk SSSR, Neorgan. Mat.,7, No. 1, 67 (1971).

    Google Scholar 

  8. G. M. Klimashin, A. I. Avgustinik, and G. V. Smirnov, Izv. Akad. Nauk SSSR, Neorgan. Mat.,8, No. 5, 843 (1972).

    Google Scholar 

  9. A. S. Borukhovich, L. B. Dubrovskaya, I. I. Matveenko, and S. S. Ordan'yan, Izv. Akad. Nauk SSSR, Neorgan. Mat.,9, No. 5, 791 (1973).

    Google Scholar 

  10. G. V. Smirnov, “An investigation of three-component alloys of titanium and zirconium with two metalloids and development of a process for the manufacture of composites of high wear resistance,” Candidate's Dissertation, LTI im. Lensoveta, Leningrad (1972).

    Google Scholar 

  11. I. N. Danisina, Yu. N. Vil'k, R. G. Avarbé, Yu. A. Omel'chenko, and T. P. Ryzhkova, Zh. Prikl. Khim.,41, No. 3, 492 (1968).

    Google Scholar 

  12. T. A. Nikol'skaya, Yu. N. Vil'k, and R. G. Avarbé, Poroshk. Metall., No. 5 (1965).

  13. G. V. Samsonov, A. T. Pilipenko, and T. N. Nazarchuk, Analysis of Refractory Compounds [in Russian], Metallurgizdat, Moscow (1962).

    Google Scholar 

  14. E. K. Storms, Refractory Carbides, Academic Press, New York (1967).

    Google Scholar 

  15. J. T. Waber, P. Chiotti, and W. N. Miner, International Symposium on Compounds of Interest in Nuclear Reactor Technology (editors, P. Costa and R. R. Conte), Pt. III, Met. Soc. Am. Inst. Mining, Met., Petrol. Engr. (1964).

  16. A. E. Vol, Structure and Properties of Binary Metallic Systems [in Russian], Vol. 1, Fizmatgiz, Moscow (1959).

    Google Scholar 

  17. H. Bittner and H. Goretzki, Monatsh. Chem.,93, No. 5, 1000 (1962).

    Google Scholar 

  18. J. T. Norton and R. K. Lewis, Rept. No. 63-18389, Advanced Metals Research Corp., Somerville, Mass.

  19. E. Rudy et al., Rept. AFML-TR-65-2, Pt. I, No. 2, Air Force Materials Laboratory, Research and Technology Division, Air Force System Command, Wright-Patterson, A. F. A., Ohio (1965).

    Google Scholar 

  20. P. Griveson, Proc. Br. Ceram. Soc.,8, 137 (1967).

    Google Scholar 

  21. M. P. Arbuzov, B. V. Khaenko, É. T. Kachkovskaya, and M. D. Lyutaya, in: Methods of Preparation, Properties, and Applications of Nitrides [in Russian], Nauk. Dumka, Kiev (1972), p. 61.

    Google Scholar 

  22. L. Ramqvist, Jernkontorets Ann.,153, 159 (1969).

    Google Scholar 

  23. L. E. Toth, Transition Metal Carbides and Nitrides, Academic Press, New York (1971).

    Google Scholar 

  24. Ya. S. Umanskii, X-Ray Diffraction of Metals [in Russian], Metallurgizdat, Moscow (1960), p. 342.

    Google Scholar 

  25. A Set of Programs for the Small Mir Computer, Vol. 2, Book II, Determination of an Approximating Polynomial by the Least-Squares Method [in Russian], Nauk. Dumka, Kiev (1971), p. 199.

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Poroshkovaya Metallurgiya, No. 12(168), pp. 42–48, December, 1976.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vil'k, Y.N., Danisina, I.N. Structural parameters and X-ray and pycnometric densities of titanium carbonitride in its homogeneity range. Powder Metall Met Ceram 15, 932–937 (1976). https://doi.org/10.1007/BF01205802

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01205802

Keywords

Navigation