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Experimental evidence for the surface change of solid state copper ion-selective electrodes in chloride medium

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Abstract

The surface changes and potentiometric response of three copper ion-selective membranes (CuS precipitate-based, CuS/Ag2S precipitate based and CuS mineral (covellite)-based) were studied after pretreatment in chloride ion containing solutions. The composition change of the membranes was identified by X-ray photoelectron spectroscopy (XPS). A correlation between surface change and response function was proved.

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Authors and Affiliations

  1. Research Group for Technical Analytical Chemistry of the Hungarian Academy of Sciences, Institute for General and Analytical Chemistry, Technical University, Geliért tér 4, H-1502, Budapest XI, Hungary

    Etelka G. Harsányi, Klára Tóth & Ernő Pungor

  2. Institute for Experimental Physics, Technical University, A-1060, Vienna, Austria

    Maria F. Ebel

Authors
  1. Etelka G. Harsányi
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  2. Klára Tóth
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  3. Ernő Pungor
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  4. Maria F. Ebel
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Harsányi, E.G., Tóth, K., Pungor, E. et al. Experimental evidence for the surface change of solid state copper ion-selective electrodes in chloride medium. Mikrochim Acta 92, 177–186 (1987). https://doi.org/10.1007/BF01201837

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  • DOI: https://doi.org/10.1007/BF01201837

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